JEE MainChemistryBiomoleculesMCQ+4 / −1
When sugar 'X' is boiled with dilute in alcoholic solution, two isomers 'A' and 'B' are formed. 'A' on oxidation with yields saccharic acid where as 'B' is laevorotatory. The compound 'X' is :
- AMaltose
- BSucrose
- CLactose
- DStarch
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Correct answer: B
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Identify what happens on boiling with dilute in alcoholic solution
Acid hydrolysis of a disaccharide gives its constituent monosaccharides.
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Use the clue about products and
We are told that two isomers and are formed.
- on oxidation with gives saccharic acid.
- Saccharic acid is obtained by oxidation of glucose.
Therefore,
- is laevorotatory.
- The common monosaccharide formed in hydrolysis of sucrose along with glucose is fructose, which is laevorotatory.
Therefore,
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Now identify sugar
The sugar that on hydrolysis gives glucose + fructose is sucrose.
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Check the options
- A: Maltose gives two units of glucose, not glucose + fructose.
- B: Sucrose gives glucose and fructose. Correct.
- C: Lactose gives glucose and galactose.
- D: Starch gives glucose units only on hydrolysis.
-
Conclusion
Hence,
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