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Biomolecules question

2022 · 28 Jun · Shift 2 · Q12
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Biomolecules question

2022 · 28 Jun · Shift 2 · Q12

JEE MainChemistryBiomoleculesMCQ+4 / −1
When sugar 'X' is boiled with dilute H2SO4H_2SO_4H2​SO4​ in alcoholic solution, two isomers 'A' and 'B' are formed. 'A' on oxidation with HNO3HNO_3HNO3​ yields saccharic acid where as 'B' is laevorotatory. The compound 'X' is :
  1. A
    Maltose
  2. B
    Sucrose
  3. C
    Lactose
  4. D
    Starch
View written solutionFree

Correct answer: B

  1. Identify what happens on boiling with dilute H2SO4H_2SO_4H2​SO4​ in alcoholic solution

    Acid hydrolysis of a disaccharide gives its constituent monosaccharides.

  2. Use the clue about products AAA and BBB

    We are told that two isomers AAA and BBB are formed.

    • AAA on oxidation with HNO3HNO_3HNO3​ gives saccharic acid.
    • Saccharic acid is obtained by oxidation of glucose.

    Therefore, A=glucoseA = \text{glucose}A=glucose

    • BBB is laevorotatory.
    • The common monosaccharide formed in hydrolysis of sucrose along with glucose is fructose, which is laevorotatory.

    Therefore, B=fructoseB = \text{fructose}B=fructose

  3. Now identify sugar XXX

    The sugar that on hydrolysis gives glucose + fructose is sucrose.

    sucrose→alcoholic solutiondil. H2SO4glucose+fructose\text{sucrose} \xrightarrow[\text{alcoholic solution}]{\text{dil. }H_2SO_4} \text{glucose} + \text{fructose}sucrosedil. H2​SO4​alcoholic solution​glucose+fructose

  4. Check the options

    • A: Maltose →\to→ gives two units of glucose, not glucose + fructose.
    • B: Sucrose →\to→ gives glucose and fructose. Correct.
    • C: Lactose →\to→ gives glucose and galactose.
    • D: Starch →\to→ gives glucose units only on hydrolysis.
  5. Conclusion

    Hence, X=sucroseX = \text{sucrose}X=sucrose

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