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Aldehydes Ketones and Carboxylic Acids question

2025 · 28 Jan · Shift 1 · Q6
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Aldehydes Ketones and Carboxylic Acids question

2025 · 28 Jan · Shift 1 · Q6

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMultiple correct+4 / −1
A molecule ("P") on treatment with acid undergoes rearrangement and gives ("Q"). ("Q") on ozonolysis followed by reflux under alkaline condition gives (" RRR"). The structure of ("RRR ") is given below. JEE Main 2025 (Online) 28th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 14 English The structure of ("P") is
  1. A
    JEE Main 2025 (Online) 28th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 14 English Option 1
  2. B
    JEE Main 2025 (Online) 28th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 14 English Option 2
  3. C
    JEE Main 2025 (Online) 28th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 14 English Option 3
  4. D
    JEE Main 2025 (Online) 28th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 14 English Option 4
View written solutionFree

Correct answer: A, D

The question refers to structures of PPP, QQQ, RRR, and options AAA–DDD, but in the provided prompt the actual structural diagrams are missing.

So, the key chemical information needed to solve the problem is unavailable:

  1. The structure of RRR is said to be “given below”, but it is not present.
  2. The structures of options AAA, BBB, CCC, and DDD are also not shown.

Without those structures, it is impossible to:

  • determine what rearrangement P→H+QP \xrightarrow{H^+} QPH+​Q undergoes,
  • infer QQQ from the ozonolysis/reflux-alkaline products,
  • and match the valid starting structures among the options.

What would normally be done

If the structures were visible, the method would be:

  1. Identify QQQ from the given product RRR using ozonolysis.
  2. Since ozonolysis followed by alkaline reflux often cleaves alkenes to carbonyl compounds, then further transforms aldehydes under basic oxidative conditions, we would reconstruct the alkene QQQ.
  3. Then we would check which candidate structures PPP can undergo acid-catalyzed rearrangement to form that alkene or precursor QQQ.
  4. Since this is MCQM, each option would be tested independently.

Conclusion

Because the actual molecular structures are missing from the prompt, the problem cannot be solved rigorously from the provided information alone.

However, the stored correct answer is given as A, D. Since I cannot independently verify it without the structures, I cannot honestly claim agreement based on derivation.

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