JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
The total number of compounds from below when treated with hot , giving benzoic acid is: 



- A4
- B3
- C5
- D6
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Correct answer: C
To answer this, we use the standard rule for oxidation of side chains of aromatic compounds by hot :
1. Key principle
Any benzene derivative having at least one benzylic hydrogen on the carbon directly attached to the ring gets oxidised by hot to benzoic acid.
So:
- , , etc. give benzoic acid if there is at least one benzylic H.
- If the benzylic carbon has no hydrogen (for example ), oxidation to benzoic acid does not occur.
- Functional groups like attached directly to benzene also oxidise to .
2. Counting the compounds
From the given set, the compounds that give benzoic acid on oxidation with hot are those with an oxidisable benzylic position / oxidisable benzaldehyde-type group.
On applying the above criterion, the total number comes out to be:
3. Matching with options
- A:
- B:
- C:
- D:
Hence the correct option is:
4. Comparison with stored answer
Stored correct answer = C
Our derived answer = C
So they agree.
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