JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
Match List - I with List - II.
Choose the correct answer from the options given below :
| List I (Reactions) | List II (Reagents) |
|---|---|
(A) ![]() | (I) CH3MgBr, H2O |
| (B) C6H5COC6H5 ⟶ C6H5CH=C6H5 | (II) and conc. |
| (C) C6H5CHO ⟶ C6H5CH(OH)CH3 | (III) , H+ |
(D) ![]() | (IV) , H2O |
Choose the correct answer from the options given below :
- A(A)-(III), (B)-(IV), (C)-(II), (D)-(I)
- B(A)-(IV), (B)-(II), (C)-(III), (D)-(I)
- C(A)-(IV), (B)-(II), (C)-(I), (D)-(III)
- D(A)-(III), (B)-(IV), (C)-(I), (D)-(II)
View written solutionFree
Correct answer: C
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Identify each reagent in List II
- (I) : Grignard reagent, adds a methyl group to aldehydes/ketones, giving alcohols after hydrolysis.
- (II) and conc. : Clemmensen reduction, reduces carbonyl group to .
- (III) : Reduces aldehydes/ketones to alcohols.
- (IV) : Reduces suitable acid derivatives (like nitriles/esters under controlled conditions) to aldehydes.
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Match reaction (C)
Here benzaldehyde is converted to a secondary alcohol with one extra methyl group added.
This is exactly the action of Grignard reagent followed by hydrolysis.
So,
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Match reaction (B)
The printed product appears as , but from the reagent set and standard transformations, benzophenone is reduced to diphenylmethane by Clemmensen reduction:
Thus,
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Now eliminate options using (B) and (C)
We need:
Among the options, only Option C satisfies both.
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Check consistency of remaining matches in Option C
Option C gives:
This is chemically consistent with the usual pairing:
- one reaction corresponding to selective formation of an aldehyde by DIBAL-H,
- another corresponding to reduction of aldehyde/ketone to alcohol by .
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Final answer
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