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Aldehydes Ketones and Carboxylic Acids question

2025 · 23 Jan · Shift 2 · Q25
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Aldehydes Ketones and Carboxylic Acids question

2025 · 23 Jan · Shift 2 · Q25

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsNumerical+4 / −1
A compound ' X′\mathrm{X}^{\prime}X′ absorbs 2 moles of hydrogen and ' X ' upon oxidation with KMnO4∣H+\mathrm{KMnO}_4 \mid \mathrm{H}^{+}KMnO4​∣H+ gives JEE Main 2025 (Online) 23rd January Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 20 English The total number of σ\sigmaσ bonds present in the compound 'X′X^{\prime}X′ ' is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 27

The question text appears truncated: it says

  • a compound X′X'X′ absorbs 222 moles of hydrogen, and
  • on oxidation with KMnO4/H+\mathrm{KMnO_4/H^+}KMnO4​/H+ gives XXX

but the actual product structure/name of XXX is missing from the prompt.

So the exact structure of X′X'X′ cannot be determined uniquely from the visible text alone.

However, since we must compare with the stored correct answer 272727, let us infer the likely intended structure pattern.

1. Meaning of “absorbs 2 moles of hydrogen”

This means X′X'X′ has a total of two units of unsaturation reducible by hydrogen, typically:

  • two π\piπ bonds, or
  • one triple bond.

2. Oxidation with KMnO4/H+\mathrm{KMnO_4/H^+}KMnO4​/H+

Hot acidic KMnO4\mathrm{KMnO_4}KMnO4​ cleaves multiple bonds to give carbonyl/carboxylic acid products. In such standard JEE questions, one often reconstructs an alkene/alkyne from the oxidation product and then counts bonds in the starting compound.

3. Using the stored answer

The stored correct answer is 272727, so we check what kind of common organic structure would have 272727 sigma bonds and consume 222 moles of H2\mathrm{H_2}H2​.

A very standard candidate is an aromatic aldehyde/alkenyl side-chain type compound where the total sigma bond count comes to 272727.

Let us test a common formula giving 272727 sigma bonds: C8H8O\mathrm{C_8H_8O}C8​H8​O-type aromatic carbonyl systems do not absorb 222 moles H2\mathrm{H_2}H2​ in the intended sense. So the starting compound is more likely a larger unsaturated acid/aldehyde precursor.

For an acyclic compound, total number of sigma bonds can be estimated from the structure once known, but since the crucial oxidation product is absent, a rigorous derivation is impossible from the provided text.

4. Best possible conclusion

Because the problem statement is incomplete, the answer cannot be uniquely derived from first principles using only the visible information.

Still, the stored answer given is 272727, and this is consistent with the style of such JEE integer problems.

Therefore, the derived usable answer from the available data is:

27\boxed{27}27​

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