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Thermodynamics question

2021 · Shift 2 · Q17
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Thermodynamics question

2021 · Shift 2 · Q17

JEE AdvancedChemistryThermodynamicsNumerical+4 / −1
One mole of an ideal gas at 900 K, undergoes two reversible processes, I followed by II, as shown below. If the work done by the gas in the two processes are same, the value of ln⁡V3V2\ln {{{V_3}} \over {{V_2}}}lnV2​V3​​ is ‾\underline{\hspace{2cm}}​. JEE Advanced 2021 Paper 2 Online Chemistry - Thermodynamics Question 19 English (U : internal energy, S : entropy, p : pressure, V : volume, R : gas constant) (Given : molar heat capacity at constant volume, CV,m of the gas is 52{5 \over 2}25​ R)
Numerical answer
View written solutionFree

Correct answer: 10

  1. Identify the two reversible processes from the diagram

For one mole of an ideal gas initially at T1=900 KT_1=900\,\text{K}T1​=900K:

  • Process I is shown on a UUU vs SSS plot.
  • Process II is shown on a ppp vs VVV plot.

We use the fact that for a reversible process, dU=TdS−pdVdU = TdS - pdVdU=TdS−pdV so on a UUU-SSS diagram, a vertical line means S=constantS=\text{constant}S=constant, i.e. a reversible adiabatic (isentropic) process.

Thus process I is reversible adiabatic from state 1 to state 2.

Process II is shown on a ppp-VVV plot as a horizontal line, hence it is isobaric from state 2 to state 3.


  1. Work done in Process I (reversible adiabatic)

For one mole of ideal gas, U=nCVT=CVTU = nC_VT = C_VTU=nCV​T=CV​T with CV=52RC_V = \frac{5}{2}RCV​=25​R

In a reversible adiabatic process, q=0  ⟹  WI=−ΔU=CV(T1−T2)q=0 \implies W_I = -\Delta U = C_V(T_1-T_2)q=0⟹WI​=−ΔU=CV​(T1​−T2​)

From the diagram, the final temperature after process I is T2=300 KT_2=300\,\text{K}T2​=300K. Hence, WI=52R(900−300)W_I = \frac{5}{2}R(900-300)WI​=25​R(900−300) WI=52R⋅600=1500RW_I = \frac{5}{2}R\cdot 600 = 1500RWI​=25​R⋅600=1500R


  1. Work done in Process II (isobaric)

For one mole of ideal gas in a reversible isobaric process, WII=p(V3−V2)W_{II} = p(V_3-V_2)WII​=p(V3​−V2​) Using pV=RTpV=RTpV=RT, pV2=RT2,pV3=RT3pV_2 = RT_2, \qquad pV_3 = RT_3pV2​=RT2​,pV3​=RT3​ So, WII=R(T3−T2)W_{II} = R(T_3-T_2)WII​=R(T3​−T2​)

Given that the work done in the two processes is same, WI=WIIW_I=W_{II}WI​=WII​ Therefore, 1500R=R(T3−T2)1500R = R(T_3-T_2)1500R=R(T3​−T2​) T3−T2=1500T_3-T_2 = 1500T3​−T2​=1500 Since T2=300 KT_2=300\,\text{K}T2​=300K, T3=1800 KT_3 = 1800\,\text{K}T3​=1800K


  1. Find ln⁡(V3V2)\ln\left(\dfrac{V_3}{V_2}\right)ln(V2​V3​​)

Process II is isobaric, so for ideal gas, V3V2=T3T2\frac{V_3}{V_2} = \frac{T_3}{T_2}V2​V3​​=T2​T3​​ Thus, V3V2=1800300=6\frac{V_3}{V_2} = \frac{1800}{300}=6V2​V3​​=3001800​=6 Hence, ln⁡(V3V2)=ln⁡6\ln\left(\frac{V_3}{V_2}\right)=\ln 6ln(V2​V3​​)=ln6

Now, ln⁡6≈1.79\ln 6 \approx 1.79ln6≈1.79

This is not equal to 10.


  1. Check consistency with the intended diagram information

A standard form of this problem usually has process I as an isothermal or some other path leading to a much larger work value, which could produce ln⁡(V3V2)=10\ln\left(\frac{V_3}{V_2}\right)=10ln(V2​V3​​)=10 But with the thermodynamic interpretation above, the result is clearly ln⁡(V3V2)=ln⁡6\ln\left(\frac{V_3}{V_2}\right)=\ln 6ln(V2​V3​​)=ln6 not an integer.

Since the question is of integer type, it strongly suggests that either:

  • some diagram information is missing from the prompt, or
  • the stored correct answer corresponds to a different figure.

With the currently available information, the mathematically derived result is: ln⁡(V3V2)=ln⁡6≈1.79\ln\left(\frac{V_3}{V_2}\right)=\ln 6 \approx 1.79ln(V2​V3​​)=ln6≈1.79

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