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Correct answer: 3OR2
- Identify the reaction between potassium iodide and potassium ferricyanide
Potassium ferricyanide is , containing the complex ion .
On adding iodide ions, a reversible redox reaction occurs:
In excess iodide, the iodine formed combines with iodide to give triiodide:
So the overall reversible reaction becomes:
Thus the complex/species formed in solution is essentially the ferrocyanide-containing system, i.e. produced in acidic medium as the equilibrium shifts to the right.
- Why strong acid shifts equilibrium toward
In strong acidic medium, the iodine/triiodide side is favored and the redox process proceeds essentially completely, generating ferrocyanide ion .
So for the precipitation step, the relevant anion is:
- Reaction with zinc chloride in slightly acidic medium
Zinc ion gives a sparingly soluble zinc ferrocyanide with ferrocyanide ion. The known insoluble zinc ferrocyanide is:
because charge balance requires:
Hence the precipitate is zinc ferrocyanide, containing 2 zinc ions per formula unit.
- Answer
The number of zinc ions in the molecular formula of is:
- Comparison with stored answer
The stored correct answer is given as 3 OR 2. My derived answer is 2, which matches one of the accepted answers.
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