JEE AdvancedChemistrySalt AnalysisMCQ+3 / −1
When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns light blue. Addition of aqueous to the blue solution gives a white precipitate O. Addition of aqueous dissolves O and gives an intense blue solution.The compound N is
- A
- B
- C
- D
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Correct answer: A
Step-by-Step Solution:
-
Analyze the first observation: A metal rod M is dipped into a colorless concentrated solution of compound N, and the solution turns light blue.
- The light blue color in aqueous solution is characteristic of the hydrated copper(II) ion, . This strongly suggests that the metal rod M is copper (Cu) and it gets oxidized to ions.
- For this reaction to occur, the metal M (Copper) must be more reactive than the metal cation present in compound N. The reaction is a displacement reaction: Assuming M is Cu, the reaction is:
- Let's examine the options based on the reactivity series (or standard electrode potentials). Copper can displace metals that are less reactive than it. The relevant part of the reactivity series is: .
- A: : Silver () is less reactive than copper (). So, can displace from solution. The reaction is spontaneous.
- B: : Zinc () is more reactive than . No reaction.
- C: : Aluminum () is more reactive than . No reaction.
- D: : Lead () is more reactive than . No reaction.
- Based on the first observation alone, compound N must be .
-
Analyze the second observation: Addition of aqueous to the blue solution gives a white precipitate O.
- The blue solution contains and possibly unreacted (since the initial solution was concentrated). So, the ions present are , , and .
- When is added, and ions are introduced.
- The possible precipitates are and . is soluble in water. is a well-known white precipitate.
- This observation is consistent with the solution containing ions, which confirms that N is .
-
Analyze the third observation: Addition of aqueous dissolves O and gives an intense blue solution.
- This observation involves two simultaneous reactions.
- First, the white precipitate O () dissolves in aqueous ammonia to form a soluble, colorless complex, diamminesilver(I) chloride.
- Second, the light blue ions in the solution react with aqueous ammonia to form the tetraamminecopper(II) complex ion, , which has a characteristic deep, intense blue color.
- This final observation perfectly matches the expected reactions for a system containing both and ions.
Conclusion:
All three observations consistently point to compound N being . The metal M is Cu. The precipitate O is . The intense blue color is due to the complex.
Therefore, the correct option is A.
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