JEE AdvancedChemistrySalt AnalysisNumerical+3 / −1
When potassium iodide is added to an aqueous solution of potassium ferricyanide, a reversible reaction is observed in which a complex is formed. In a strong acidic medium, the equilibrium shifts completely towards . Addition of zinc chloride to in a slightly acidic medium results in a sparingly soluble complex Q.The number of moles of potassium iodide required to produce two moles of is .
Numerical answer
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Correct answer: 2
- Identify the reversible reaction between potassium iodide and potassium ferricyanide
Potassium ferricyanide is , containing the ion .
Iodide ion acts as a reducing agent and reduces ferricyanide to ferrocyanide:
In terms of potassium salts:
So the complex formed is:
- Why does strong acidic medium shift equilibrium towards ?
In strong acid, the iodine formed is consumed by iodide to give species like /further side processes, and effectively the reaction is driven forward. The important identification remains that is potassium ferrocyanide, .
- Identify formed with zinc chloride in slightly acidic medium
Ferrocyanide gives a sparingly soluble zinc ferrocyanide with :
Thus this confirms again that contains the ferrocyanide ion.
- Find moles of KI required to produce 2 moles of
From the balanced reaction:
This shows:
Therefore,
Hence, to produce moles of , required moles of are:
- Comparison with stored answer
Derived answer =
Stored correct answer =
So they agree.
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