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Salt Analysis question

2024 · Shift 2 · Q16
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Salt Analysis question

2024 · Shift 2 · Q16

JEE AdvancedChemistrySalt AnalysisNumerical+3 / −1
When potassium iodide is added to an aqueous solution of potassium ferricyanide, a reversible reaction is observed in which a complex P\mathbf{P}P is formed. In a strong acidic medium, the equilibrium shifts completely towards P\mathbf{P}P. Addition of zinc chloride to P\mathbf{P}P in a slightly acidic medium results in a sparingly soluble complex Q.The number of moles of potassium iodide required to produce two moles of P\mathbf{P}P is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 2

  1. Identify the reversible reaction between potassium iodide and potassium ferricyanide

Potassium ferricyanide is K3[Fe(CN)6]K_3[Fe(CN)_6]K3​[Fe(CN)6​], containing the ion [Fe(CN)6]3−[Fe(CN)_6]^{3-}[Fe(CN)6​]3−.

Iodide ion I−I^-I− acts as a reducing agent and reduces ferricyanide to ferrocyanide:

2[Fe(CN)6]3−+2I−⇌2[Fe(CN)6]4−+I22[Fe(CN)_6]^{3-} + 2I^- \rightleftharpoons 2[Fe(CN)_6]^{4-} + I_22[Fe(CN)6​]3−+2I−⇌2[Fe(CN)6​]4−+I2​

In terms of potassium salts:

2K3[Fe(CN)6]+2KI⇌2K4[Fe(CN)6]+I22K_3[Fe(CN)_6] + 2KI \rightleftharpoons 2K_4[Fe(CN)_6] + I_22K3​[Fe(CN)6​]+2KI⇌2K4​[Fe(CN)6​]+I2​

So the complex P\mathbf{P}P formed is:

P=K4[Fe(CN)6]\mathbf{P} = K_4[Fe(CN)_6]P=K4​[Fe(CN)6​]

  1. Why does strong acidic medium shift equilibrium towards PPP?

In strong acid, the iodine formed is consumed by iodide to give species like I3−I_3^-I3−​/further side processes, and effectively the reaction is driven forward. The important identification remains that PPP is potassium ferrocyanide, K4[Fe(CN)6]K_4[Fe(CN)_6]K4​[Fe(CN)6​].

  1. Identify QQQ formed with zinc chloride in slightly acidic medium

Ferrocyanide gives a sparingly soluble zinc ferrocyanide with Zn2+Zn^{2+}Zn2+:

2Zn2++[Fe(CN)6]4−→Zn2[Fe(CN)6]↓2Zn^{2+} + [Fe(CN)_6]^{4-} \rightarrow Zn_2[Fe(CN)_6] \downarrow2Zn2++[Fe(CN)6​]4−→Zn2​[Fe(CN)6​]↓

Thus this confirms again that PPP contains the ferrocyanide ion.

  1. Find moles of KI required to produce 2 moles of PPP

From the balanced reaction:

2K3[Fe(CN)6]+2KI→2K4[Fe(CN)6]+I22K_3[Fe(CN)_6] + 2KI \rightarrow 2K_4[Fe(CN)_6] + I_22K3​[Fe(CN)6​]+2KI→2K4​[Fe(CN)6​]+I2​

This shows:

2 mol KI→2 mol P2\text{ mol } KI \rightarrow 2\text{ mol } P2 mol KI→2 mol P

Therefore,

1 mol KI→1 mol P1\text{ mol } KI \rightarrow 1\text{ mol } P1 mol KI→1 mol P

Hence, to produce 222 moles of PPP, required moles of KIKIKI are:

2\boxed{2}2​

  1. Comparison with stored answer

Derived answer = 222

Stored correct answer = 222

So they agree.

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