- AFe
- BCu
- CNi
- DCo
View written solutionFree
Correct answer: B
Step-by-step solution:
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Analyze the first observation: A metal rod M is dipped into a colorless concentrated aqueous solution of compound N, and the solution turns light blue.
- This color change indicates that the metal M is being oxidized and entering the solution as a hydrated metal ion that has a characteristic blue color.
- The light blue color of an aqueous solution is a classic sign of the hydrated copper(II) ion, .
- This suggests that the metal rod M is Copper (Cu). The oxidation reaction is: .
- For this reaction to occur, the cation in the solution of compound N must have a higher standard reduction potential than copper (). Since the solution of N is colorless, a good candidate for the cation in N is (). So, compound N could be silver nitrate, .
- The overall reaction would be: . The solution turns light blue due to the formation of .
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Analyze the second observation: Addition of aqueous to the blue solution gives a white precipitate O.
- The blue solution now contains ions and, if the reaction in step 1 was not complete, some unreacted cations from compound N (e.g., ).
- When is added, it provides ions.
- ions form which is soluble in water.
- ions react with ions to form a characteristic white precipitate of silver chloride, .
- Reaction: .
- This observation is consistent with our hypothesis that N is an salt and the white precipitate O is .
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Analyze the third observation: Addition of aqueous dissolves O and gives an intense blue solution.
- This step involves two reactions happening in the mixture.
- Reaction 1: Dissolution of precipitate O. The white precipitate O () reacts with aqueous ammonia to form a soluble complex, diamminesilver(I) chloride. This is a characteristic test for silver halides (except AgI). This explains why the precipitate O dissolves.
- Reaction 2: Formation of an intense blue solution. The ions in the solution react with aqueous ammonia to form the tetraamminecopper(II) complex ion, , which has a characteristic deep blue or intense blue color. This explains the formation of the intense blue solution.
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Evaluate other options:
- A: Fe (Iron): Iron forms (light green) or (yellow-brown) ions in solution, not light blue.
- C: Ni (Nickel): Nickel forms ions, which are green in aqueous solution, not light blue.
- D: Co (Cobalt): Cobalt forms ions, which are pink in aqueous solution, not light blue.
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Conclusion: The entire sequence of reactions and color changes is perfectly consistent with the metal M being Copper (Cu). The properties observed (light blue solution with , formation of precipitate, dissolution of with ammonia, and formation of deep blue complex) are all standard qualitative analysis tests for copper and silver ions.
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