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Salt Analysis question

2011 · Shift 1 · Q18
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Salt Analysis question

2011 · Shift 1 · Q18

JEE AdvancedChemistrySalt AnalysisMCQ+3 / −1
When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns light blue. Addition of aqueous NaClNaClNaCl to the blue solution gives a white precipitate O. Addition of aqueous NH3NH_3NH3​ dissolves O and gives an intense blue solution.The metal rod M is
  1. A
    Fe
  2. B
    Cu
  3. C
    Ni
  4. D
    Co
View written solutionFree

Correct answer: B

Step-by-step solution:

  1. Analyze the first observation: A metal rod M is dipped into a colorless concentrated aqueous solution of compound N, and the solution turns light blue.

    • This color change indicates that the metal M is being oxidized and entering the solution as a hydrated metal ion that has a characteristic blue color.
    • The light blue color of an aqueous solution is a classic sign of the hydrated copper(II) ion, [Cu(H2O)6]2+[Cu(H_2O)_6]^{2+}[Cu(H2​O)6​]2+.
    • This suggests that the metal rod M is Copper (Cu). The oxidation reaction is: Cu(s)→Cu2+(aq)+2e−Cu(s) \rightarrow Cu^{2+}(aq) + 2e^-Cu(s)→Cu2+(aq)+2e−.
    • For this reaction to occur, the cation in the solution of compound N must have a higher standard reduction potential than copper (ECu2+/Cu0=+0.34VE^0_{Cu^{2+}/Cu} = +0.34 VECu2+/Cu0​=+0.34V). Since the solution of N is colorless, a good candidate for the cation in N is Ag+Ag^+Ag+ (EAg+/Ag0=+0.80VE^0_{Ag^+/Ag} = +0.80 VEAg+/Ag0​=+0.80V). So, compound N could be silver nitrate, AgNO3AgNO_3AgNO3​.
    • The overall reaction would be: Cu(s)+2Ag+(aq)→Cu2+(aq)+2Ag(s)Cu(s) + 2Ag^+(aq) \rightarrow Cu^{2+}(aq) + 2Ag(s)Cu(s)+2Ag+(aq)→Cu2+(aq)+2Ag(s). The solution turns light blue due to the formation of Cu2+(aq)Cu^{2+}(aq)Cu2+(aq).
  2. Analyze the second observation: Addition of aqueous NaClNaClNaCl to the blue solution gives a white precipitate O.

    • The blue solution now contains Cu2+Cu^{2+}Cu2+ ions and, if the reaction in step 1 was not complete, some unreacted cations from compound N (e.g., Ag+Ag^+Ag+).
    • When NaClNaClNaCl is added, it provides Cl−Cl^-Cl− ions.
    • Cu2+Cu^{2+}Cu2+ ions form CuCl2CuCl_2CuCl2​ which is soluble in water.
    • Ag+Ag^+Ag+ ions react with Cl−Cl^-Cl− ions to form a characteristic white precipitate of silver chloride, AgClAgClAgCl.
    • Reaction: Ag+(aq)+Cl−(aq)→AgCl(s)Ag^+(aq) + Cl^-(aq) \rightarrow AgCl(s)Ag+(aq)+Cl−(aq)→AgCl(s).
    • This observation is consistent with our hypothesis that N is an Ag+Ag^+Ag+ salt and the white precipitate O is AgClAgClAgCl.
  3. Analyze the third observation: Addition of aqueous NH3NH_3NH3​ dissolves O and gives an intense blue solution.

    • This step involves two reactions happening in the mixture.
    • Reaction 1: Dissolution of precipitate O. The white precipitate O (AgClAgClAgCl) reacts with aqueous ammonia to form a soluble complex, diamminesilver(I) chloride. This is a characteristic test for silver halides (except AgI). AgCl(s)+2NH3(aq)→[Ag(NH3)2]+(aq)+Cl−(aq)AgCl(s) + 2NH_3(aq) \rightarrow [Ag(NH_3)_2]^+(aq) + Cl^-(aq)AgCl(s)+2NH3​(aq)→[Ag(NH3​)2​]+(aq)+Cl−(aq) This explains why the precipitate O dissolves.
    • Reaction 2: Formation of an intense blue solution. The Cu2+Cu^{2+}Cu2+ ions in the solution react with aqueous ammonia to form the tetraamminecopper(II) complex ion, [Cu(NH3)4]2+[Cu(NH_3)_4]^{2+}[Cu(NH3​)4​]2+, which has a characteristic deep blue or intense blue color. Cu2+(aq)+4NH3(aq)→[Cu(NH3)4]2+(aq)Cu^{2+}(aq) + 4NH_3(aq) \rightarrow [Cu(NH_3)_4]^{2+}(aq)Cu2+(aq)+4NH3​(aq)→[Cu(NH3​)4​]2+(aq) This explains the formation of the intense blue solution.
  4. Evaluate other options:

    • A: Fe (Iron): Iron forms Fe2+Fe^{2+}Fe2+ (light green) or Fe3+Fe^{3+}Fe3+ (yellow-brown) ions in solution, not light blue.
    • C: Ni (Nickel): Nickel forms Ni2+Ni^{2+}Ni2+ ions, which are green in aqueous solution, not light blue.
    • D: Co (Cobalt): Cobalt forms Co2+Co^{2+}Co2+ ions, which are pink in aqueous solution, not light blue.
  5. Conclusion: The entire sequence of reactions and color changes is perfectly consistent with the metal M being Copper (Cu). The properties observed (light blue solution with Cu2+Cu^{2+}Cu2+, formation of AgClAgClAgCl precipitate, dissolution of AgClAgClAgCl with ammonia, and formation of deep blue [Cu(NH3)4]2+[Cu(NH_3)_4]^{2+}[Cu(NH3​)4​]2+ complex) are all standard qualitative analysis tests for copper and silver ions.

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