View written solutionFree
Correct answer: 280
Step-by-step Derivation:
-
Identify the Monomers of Nylon 6,6: Nylon 6,6 is a condensation polymer formed from two monomers, each containing 6 carbon atoms. These monomers are:
- Hexamethylenediamine:
H₂N-(CH₂)₆-NH₂ - Adipic acid:
HOOC-(CH₂)₄-COOH
- Hexamethylenediamine:
-
Identify the Monomer (X): The problem states that monomer (X) gives a positive carbylamine test. The carbylamine test (also known as Hoffmann's isocyanide test) is a specific test for primary amines (
-NH₂group).- Hexamethylenediamine has two primary amine groups, so it will give a positive carbylamine test.
- Adipic acid is a carboxylic acid and does not have an amine group, so it will give a negative test. Therefore, the monomer (X) is hexamethylenediamine.
-
Determine the Chemical Formula of Monomer (X): The chemical formula for hexamethylenediamine,
H₂N-(CH₂)₆-NH₂, isC₆H₁₆N₂. From the formula, we can see that one molecule of hexamethylenediamine contains two nitrogen atoms. -
Relate Monomer (X) to Nitrogen Gas in the Dumas Method: The Dumas method is used for the quantitative estimation of nitrogen. In this method, all the nitrogen present in the organic compound is converted into nitrogen gas (
N₂). The monomer (X) has the formulaC₆H₁₆N₂. It contains 2 nitrogen atoms per molecule. These 2 nitrogen atoms combine to form one molecule of nitrogen gas (N₂). So, the stoichiometric relationship is: On a molar basis: -
Calculate the Moles of Nitrogen Gas Evolved: We are given that 10 moles of monomer (X) are analyzed. Based on the stoichiometry from Step 4, 10 moles of X will produce 10 moles of
N₂gas. Moles ofN₂evolved = 10 mol. -
Calculate the Mass of Nitrogen Gas Evolved: The mass of a substance is calculated by multiplying its moles by its molar mass.
- Atomic mass of Nitrogen (N) = 14 amu. So, the molar mass of N is 14 g/mol.
- Molar mass of nitrogen gas (
N₂) =2 × 14g/mol =28g/mol.
Mass of
N₂evolved = Moles ofN₂× Molar mass ofN₂Mass ofN₂evolved = Mass ofN₂evolved =280g.
Final Answer:
The amount of nitrogen gas evolved is 280 grams.
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