Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Isolation of Elements question

2016 · Shift 2 · Q1
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Advanced
  3. /Chemistry
  4. /Isolation of Elements
  5. /2016 · Shift 2 · Q1

Isolation of Elements question

2016 · Shift 2 · Q1

JEE AdvancedChemistryIsolation of ElementsMultiple correct+4 / −2
Extraction of copper from copper pyrite (CuFeS2CuFeS_2CuFeS2​) involves
  1. A
    crushing followed by concentration of the ore by froth flotation
  2. B
    removal of iron as slag
  3. C
    self-reduction step to produce 'blister copper' following evolution of SO2SO_2SO2​
  4. D
    refining of ‘blister copper’ by carbon reduction
View written solutionFree

Correct answer: A, B, C

  1. Identify the metallurgy involved

Copper is commonly extracted from copper pyrite, CuFeS2CuFeS_2CuFeS2​, a sulphide ore. The usual steps in extraction are:

  • Crushing and grinding
  • Concentration by froth flotation
  • Roasting/smelting
  • Removal of iron as slag
  • Formation of copper matte
  • Self-reduction to give blister copper
  • Electrolytic refining

  1. Check Option A

A: crushing followed by concentration of the ore by froth flotation

Since CuFeS2CuFeS_2CuFeS2​ is a sulphide ore, it is concentrated by froth flotation method after crushing and grinding.

So, A is correct.


  1. Check Option B

B: removal of iron as slag

During smelting, iron sulphide gets oxidized:

2FeS+3O2→2FeO+2SO22FeS + 3O_2 \rightarrow 2FeO + 2SO_22FeS+3O2​→2FeO+2SO2​

Then silica is added as flux, and iron oxide is removed as slag:

FeO+SiO2→FeSiO3FeO + SiO_2 \rightarrow FeSiO_3FeO+SiO2​→FeSiO3​

Thus iron is removed as ferrous silicate slag.

So, B is correct.


  1. Check Option C

C: self-reduction step to produce 'blister copper' following evolution of SO2SO_2SO2​

After formation of copper matte, some copper sulphide and copper oxide are present. Then self-reduction occurs:

2Cu2O+Cu2S→6Cu+SO22Cu_2O + Cu_2S \rightarrow 6Cu + SO_22Cu2​O+Cu2​S→6Cu+SO2​

This produces blister copper, and SO2SO_2SO2​ is evolved. The blister appearance is due to escaping SO2SO_2SO2​ gas.

So, C is correct.


  1. Check Option D

D: refining of ‘blister copper’ by carbon reduction

Blister copper is not refined by carbon reduction. It is refined mainly by electrolytic refining.

Hence, D is incorrect.


  1. Final answer

The correct options are:

A, B, C\boxed{A,\ B,\ C}A, B, C​


  1. Comparison with stored correct answer

Stored correct answer: A, B, C

My derived answer matches the stored correct answer.

PreviousNext

More from Isolation of Elements

  • Match the anionic species given in Column-I that are present in the ore(s) given in Column-II Includes table2015 · MCQ
  • Copper is purified by electrolytic refining of blister copper. The correct statement(s) about this process is(are)2015 · Multiple correct
  • Sulphide ores are common for the metals2013 · MCQ
  • The carbon–based reduction method is NOT used for the extraction of2013 · Multiple correct
  • In the cyanide extraction process of silver from argentite ore, the oxidising and reducing agents used are2012 · MCQ
  • Extraction of metal from the ore cassiterite involves2011 · Multiple correct
  • Oxidation states of the metal in the minerals haematite and magnetite, respectively are2011 · MCQ
  • Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copper inculcated chalcanthite (CuSO 4​ . 5H 2​ O), atacamite (Cu 2​ Cl(OH) 3​), cuprite (Cu 2​ O),…2010 · MCQ