JEE AdvancedChemistryIsolation of ElementsMultiple correct+4 / −2
Copper is purified by electrolytic refining of blister copper. The correct statement(s) about this process is(are)
- AImpure Cu strip is used as cathode
- BAcidified aqueous CuSO is used as electrolyte
- CPure Cu deposits at cathode
- DImpurities settle as anode – mud
View written solutionFree
Correct answer: B, C, D
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Recall the electrolytic refining of copper
In electrolytic refining of copper:
- Impure copper is made the anode
- Pure copper sheet is made the cathode
- The electrolyte is acidified aqueous
The electrode reactions are:
At anode:
At cathode:
-
Evaluate each option
A: Impure Cu strip is used as cathode
- This is incorrect.
- In copper refining, impure copper is the anode, not the cathode.
Therefore, A is false.
B: Acidified aqueous is used as electrolyte
- This is the standard electrolyte used in electrolytic refining of copper.
Therefore, B is true.
C: Pure Cu deposits at cathode
- Copper ions from solution gain electrons at the cathode and deposit as pure copper:
Therefore, C is true.
D: Impurities settle as anode–mud
- Insoluble impurities such as Ag, Au, Pt, etc. fall below the anode as anode mud.
Therefore, D is true.
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Final derived answer
The correct statements are:
-
Comparison with stored correct answer
Stored correct answer: B, C, D
My derived answer matches the stored answer.
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