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Isolation of Elements question

2015 · Shift 1 · Q2
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Isolation of Elements question

2015 · Shift 1 · Q2

JEE AdvancedChemistryIsolation of ElementsMultiple correct+4 / −2
Copper is purified by electrolytic refining of blister copper. The correct statement(s) about this process is(are)
  1. A
    Impure Cu strip is used as cathode
  2. B
    Acidified aqueous CuSO4{}_44​ is used as electrolyte
  3. C
    Pure Cu deposits at cathode
  4. D
    Impurities settle as anode – mud
View written solutionFree

Correct answer: B, C, D

  1. Recall the electrolytic refining of copper

    In electrolytic refining of copper:

    • Impure copper is made the anode
    • Pure copper sheet is made the cathode
    • The electrolyte is acidified aqueous CuSO4\mathrm{CuSO_4}CuSO4​

    The electrode reactions are:

    At anode: Cu(s)→Cu2+(aq)+2e−\mathrm{Cu(s) \rightarrow Cu^{2+}(aq) + 2e^-}Cu(s)→Cu2+(aq)+2e−

    At cathode: Cu2+(aq)+2e−→Cu(s)\mathrm{Cu^{2+}(aq) + 2e^- \rightarrow Cu(s)}Cu2+(aq)+2e−→Cu(s)

  2. Evaluate each option

    A: Impure Cu strip is used as cathode

    • This is incorrect.
    • In copper refining, impure copper is the anode, not the cathode.

    Therefore, A is false.

    B: Acidified aqueous CuSO4\mathrm{CuSO_4}CuSO4​ is used as electrolyte

    • This is the standard electrolyte used in electrolytic refining of copper.

    Therefore, B is true.

    C: Pure Cu deposits at cathode

    • Copper ions from solution gain electrons at the cathode and deposit as pure copper: Cu2++2e−→Cu\mathrm{Cu^{2+} + 2e^- \rightarrow Cu}Cu2++2e−→Cu

    Therefore, C is true.

    D: Impurities settle as anode–mud

    • Insoluble impurities such as Ag, Au, Pt, etc. fall below the anode as anode mud.

    Therefore, D is true.

  3. Final derived answer

    The correct statements are: B, C, D\boxed{\text{B, C, D}}B, C, D​

  4. Comparison with stored correct answer

    Stored correct answer: B, C, D

    My derived answer matches the stored answer.

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