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Isolation of Elements question

2011 · Shift 1 · Q7
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Isolation of Elements question

2011 · Shift 1 · Q7

JEE AdvancedChemistryIsolation of ElementsMultiple correct+2 / −0.5
Extraction of metal from the ore cassiterite involves
  1. A
    carbon reduction of an oxide ore
  2. B
    self-reduction of a sulphide ore
  3. C
    removal of copper impurity
  4. D
    removal of iron impurity
View written solutionFree

Correct answer: A, C, D

The question asks about the processes involved in the extraction of metal from cassiterite ore.

  1. Identify the Ore and Metal:

    • The ore is cassiterite.
    • The chemical formula for cassiterite is SnO2SnO_2SnO2​ (tin(IV) oxide).
    • The metal to be extracted is tin (Sn).
  2. Evaluate Option A: carbon reduction of an oxide ore

    • Cassiterite (SnO2SnO_2SnO2​) is an oxide ore of tin.
    • The primary method for extracting tin from its oxide is smelting with a reducing agent, typically carbon (in the form of coke), in a reverberatory furnace.
    • The main chemical reaction is: SnO2(s)+2C(s)→ΔSn(l)+2CO(g)SnO_2(s) + 2C(s) \xrightarrow{\Delta} Sn(l) + 2CO(g)SnO2​(s)+2C(s)Δ​Sn(l)+2CO(g)
    • This is a classic example of carbon reduction of an oxide ore. Therefore, statement A is correct.
  3. Evaluate Option B: self-reduction of a sulphide ore

    • Self-reduction is a method used for extracting metals from their sulphide ores (e.g., Cu from Cu2SCu_2SCu2​S, Pb from PbSPbSPbS). It involves partial roasting of the sulphide ore to form an oxide, which then reacts with the remaining sulphide ore to yield the metal.
    • Cassiterite is an oxide ore (SnO2SnO_2SnO2​), not a sulphide ore.
    • The reduction is carried out using an external reducing agent (carbon), not by self-reduction.
    • Therefore, statement B is incorrect.
  4. Evaluate Option D: removal of iron impurity

    • Cassiterite ore is commonly associated with impurities, with iron-containing minerals being very common. These include wolframite ((Fe,Mn)WO4(Fe,Mn)WO_4(Fe,Mn)WO4​) and iron pyrites (FeS2FeS_2FeS2​).
    • Wolframite, being magnetic, is removed by magnetic separation before smelting.
    • During smelting, any iron oxides present are also reduced by carbon to form iron metal (Fe2O3+3C→2Fe+3COFe_2O_3 + 3C \rightarrow 2Fe + 3COFe2​O3​+3C→2Fe+3CO). This iron dissolves in the molten tin.
    • The crude tin (called "black tin") is then refined to remove iron. One method is liquation, where the low-melting-point tin (m.p. 232°C) is melted and flows away from the higher-melting-point iron (m.p. 1538°C).
    • Therefore, the removal of iron impurity is a crucial part of the overall extraction process. Statement D is correct.
  5. Evaluate Option C: removal of copper impurity

    • Copper impurities, often from copper pyrites (CuFeS2CuFeS_2CuFeS2​), can also be present in cassiterite ore.
    • Similar to iron, copper will be present in the crude tin after smelting.
    • Refining processes like liquation and polling are used to remove impurities like copper and iron.
    • Therefore, the removal of copper impurity is also involved in the process. Statement C is correct.

Conclusion: The extraction of tin from cassiterite involves carbon reduction of the oxide ore (SnO2SnO_2SnO2​) and the removal of common impurities such as iron and copper. Thus, options A, C, and D correctly describe parts of the process.

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