JEE AdvancedChemistryIsolation of ElementsMultiple correct+2 / −0.5
Extraction of metal from the ore cassiterite involves
- Acarbon reduction of an oxide ore
- Bself-reduction of a sulphide ore
- Cremoval of copper impurity
- Dremoval of iron impurity
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Correct answer: A, C, D
The question asks about the processes involved in the extraction of metal from cassiterite ore.
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Identify the Ore and Metal:
- The ore is cassiterite.
- The chemical formula for cassiterite is (tin(IV) oxide).
- The metal to be extracted is tin (Sn).
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Evaluate Option A: carbon reduction of an oxide ore
- Cassiterite () is an oxide ore of tin.
- The primary method for extracting tin from its oxide is smelting with a reducing agent, typically carbon (in the form of coke), in a reverberatory furnace.
- The main chemical reaction is:
- This is a classic example of carbon reduction of an oxide ore. Therefore, statement A is correct.
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Evaluate Option B: self-reduction of a sulphide ore
- Self-reduction is a method used for extracting metals from their sulphide ores (e.g., Cu from , Pb from ). It involves partial roasting of the sulphide ore to form an oxide, which then reacts with the remaining sulphide ore to yield the metal.
- Cassiterite is an oxide ore (), not a sulphide ore.
- The reduction is carried out using an external reducing agent (carbon), not by self-reduction.
- Therefore, statement B is incorrect.
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Evaluate Option D: removal of iron impurity
- Cassiterite ore is commonly associated with impurities, with iron-containing minerals being very common. These include wolframite () and iron pyrites ().
- Wolframite, being magnetic, is removed by magnetic separation before smelting.
- During smelting, any iron oxides present are also reduced by carbon to form iron metal (). This iron dissolves in the molten tin.
- The crude tin (called "black tin") is then refined to remove iron. One method is liquation, where the low-melting-point tin (m.p. 232°C) is melted and flows away from the higher-melting-point iron (m.p. 1538°C).
- Therefore, the removal of iron impurity is a crucial part of the overall extraction process. Statement D is correct.
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Evaluate Option C: removal of copper impurity
- Copper impurities, often from copper pyrites (), can also be present in cassiterite ore.
- Similar to iron, copper will be present in the crude tin after smelting.
- Refining processes like liquation and polling are used to remove impurities like copper and iron.
- Therefore, the removal of copper impurity is also involved in the process. Statement C is correct.
Conclusion: The extraction of tin from cassiterite involves carbon reduction of the oxide ore () and the removal of common impurities such as iron and copper. Thus, options A, C, and D correctly describe parts of the process.
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