JEE AdvancedChemistryIsolation of ElementsMCQ+1 / −0.25
Oxidation states of the metal in the minerals haematite and magnetite, respectively are
- AII, III in haematite and III in magnetite
- BII, III in haematite and II in magnetite
- CII in haematite and II, III in magnetite
- DIII in haematite and II, III in magnetite
View written solutionFree
Correct answer: D
The user wants to find the oxidation states of iron in the minerals haematite and magnetite.
Step 1: Determine the chemical formulas of the minerals.
- The chemical formula for haematite is .
- The chemical formula for magnetite is .
Step 2: Calculate the oxidation state of iron in haematite ().
- The general oxidation state of oxygen (O) in oxides is -2.
- Let the oxidation state of iron (Fe) be .
- Since the overall charge of the compound is neutral (0), we can set up an equation:
- Solving for :
- Therefore, the oxidation state of iron in haematite is +III.
Step 3: Calculate the oxidation state(s) of iron in magnetite ().
- Magnetite () is a mixed oxide, which means it is composed of two different oxides of the same element.
- It can be represented as a combination of ferrous oxide () and ferric oxide ().
- Now, we determine the oxidation state of iron in each component oxide:
- In ferrous oxide (): Let the oxidation state of Fe be . The oxidation state of O is -2. The overall charge is 0. So, one iron atom is in the +II oxidation state.
- In ferric oxide (): As calculated in Step 2, the oxidation state of iron is +III. Two iron atoms are in the +III oxidation state.
- Therefore, magnetite () contains iron in two different oxidation states: +II and +III.
Step 4: Compare the findings with the given options.
- Haematite: Oxidation state is III.
- Magnetite: Oxidation states are II and III.
Let's evaluate the options:
- A: II, III in haematite and III in magnetite - Incorrect. Haematite is only III.
- B: II, III in haematite and II in magnetite - Incorrect. Haematite is only III.
- C: II in haematite and II, III in magnetite - Incorrect. Haematite is III.
- D: III in haematite and II, III in magnetite - Correct. This matches our calculated oxidation states.
Thus, the correct option is D.
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