- ACu S and FeO
- BCu O and FeO
- CCuS and Fe O
- DCu O and Fe O
View written solutionFree
Correct answer: A
Step-by-step Solution:
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Understand the Reactant and Process: The question asks for the products of the partial roasting of chalcopyrite. The chemical formula for chalcopyrite is
CuFeS₂. Roasting is a metallurgical process that involves heating a sulfide ore in the presence of air (oxygen). "Partial" roasting implies that the reaction is carried out with a limited supply of air or under controlled conditions to achieve a specific set of products, rather than complete oxidation. -
Analyze the Components of Chalcopyrite: Chalcopyrite (
CuFeS₂) can be considered as a mixed sulfide containing copper, iron, and sulfur. When heated in the presence of oxygen, both the metal sulfides can be oxidized. -
Apply Principles of Metallurgy: In the extraction of copper, the goal of the initial roasting step is to remove iron as an impurity. Iron has a higher affinity for oxygen than copper. Therefore, the iron sulfide component of the ore is preferentially oxidized over the copper sulfide component.
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Write the Chemical Reactions: The partial roasting of chalcopyrite proceeds as follows:
- Chalcopyrite (
CuFeS₂) is heated in a limited supply of air. The iron sulfide is oxidized to ferrous oxide (FeO), while the copper sulfide is converted to cuprous sulfide (Cu₂S). Sulfur is oxidized to sulfur dioxide gas (SO₂). - The overall balanced chemical equation for this process is:
- The solid product is a mixture of cuprous sulfide (
Cu₂S) and ferrous oxide (FeO), which is called "matte". The sulfur dioxide (SO₂) escapes as a gas.
- Chalcopyrite (
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Evaluate the Options: Based on the reaction products derived above, let's examine the given options:
- A: Cu₂S and FeO: This option correctly identifies the main solid products of the partial roasting of chalcopyrite. Cuprous sulfide and ferrous oxide form the matte.
- B: Cu₂O and FeO: This is incorrect. During partial roasting, copper is not oxidized to
Cu₂O. It remains in the sulfide form (Cu₂S). The conversion ofCu₂StoCu₂Ooccurs later during the Bessemerization stage for self-reduction. - C: CuS and Fe₂O₃: This is incorrect.
CuFeS₂gets converted to the more stable cuprous sulfide (Cu₂S), notCuS. Also, under the controlled conditions of partial roasting, iron is primarily oxidized to ferrous oxide (FeO), not ferric oxide (Fe₂O₃), asFeOis required for slag formation (FeSiO₃) in the next step. - D: Cu₂O and Fe₂O₃: This is incorrect for the reasons mentioned for options B and C. It represents a more complete oxidation, which is not the goal of this specific step.
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Conclusion: The partial roasting of chalcopyrite (
CuFeS₂) yields cuprous sulfide (Cu₂S) and ferrous oxide (FeO) as the main solid products. Thus, option A is the correct answer.
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