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Chemical Kinetics and Nuclear Chemistry question

2013 · Shift 2 · Q2
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Chemical Kinetics and Nuclear Chemistry question

2013 · Shift 2 · Q2

JEE AdvancedChemistryChemical Kinetics and Nuclear ChemistryMultiple correct+4 / −1
In the nuclear transmutation 9Be4Be_4Be4​ + X →\to→ 8Be4Be_4Be4​ + Y (X, Y) is (are) :
  1. A
    (γ,n)(\gamma ,n)(γ,n)
  2. B
    (p, D)
  3. C
    (n, D)
  4. D
    (γ,p)(\gamma ,p)(γ,p)
View written solutionFree

Correct answer: A, B

Introduction

The problem asks to identify the pair of particles (X, Y) that correctly completes the given nuclear transmutation reaction: 49Be+X→48Be+Y_4^9Be + X \to _4^8Be + Y49​Be+X→48​Be+Y To solve this, we must apply the laws of conservation of mass number (A) and atomic number (Z) in nuclear reactions.

  1. Conservation of Mass Number (A): The sum of the mass numbers of the reactants must equal the sum of the mass numbers of the products.
  2. Conservation of Atomic Number (Z): The sum of the atomic numbers (charges) of the reactants must equal the sum of the atomic numbers of the products.

Step-by-Step Solution

Let's represent the incoming particle X as ZAX_Z^A XZA​X and the outgoing particle Y as zaY_z^a Yza​Y. The nuclear reaction can be written as: 49Be+ZAX→48Be+zaY_4^9Be + _Z^A X \to _4^8Be + _z^a Y49​Be+ZA​X→48​Be+za​Y

Applying Conservation Laws:

  1. Conservation of Mass Number (A): 9+A=8+a9 + A = 8 + a9+A=8+a a−A=9−8a - A = 9 - 8a−A=9−8 a−A=1a - A = 1a−A=1

  2. Conservation of Atomic Number (Z): 4+Z=4+z4 + Z = 4 + z4+Z=4+z z−Z=4−4z - Z = 4 - 4z−Z=4−4 z−Z=0  ⟹  z=Zz - Z = 0 \implies z = Zz−Z=0⟹z=Z

Now, we will evaluate each option to see if it satisfies these two conditions: a - A = 1 and z = Z.

Particle Notations:

  • Gamma photon (γ\\\gammaγ): 00γ_0^0\gamma00​γ (A=0, Z=0)
  • Neutron (n): 01n_0^1n01​n (A=1, Z=0)
  • Proton (p): 11p_1^1p11​p (A=1, Z=1)
  • Deuteron (D): 12D_1^2D12​D (A=2, Z=1)

Evaluation of Options

A: (γ,n)(\gamma ,n)(γ,n)

  • X is a gamma photon (00γ_0^0\gamma00​γ), so A=0 and Z=0.
  • Y is a neutron (01n_0^1n01​n), so a=1 and z=0.

Check conditions:

  1. a - A = 1 - 0 = 1. This condition is satisfied.
  2. z=Z  ⟹  0=0z = Z \implies 0 = 0z=Z⟹0=0. This condition is satisfied. Since both conditions are met, option A is a valid solution. The reaction is: 49Be+00γ→48Be+01n_4^9Be + _0^0\gamma \to _4^8Be + _0^1n49​Be+00​γ→48​Be+01​n. This is a photodisintegration reaction.

B: (p, D)

  • X is a proton (11p_1^1p11​p), so A=1 and Z=1.
  • Y is a deuteron (12D_1^2D12​D), so a=2 and z=1.

Check conditions:

  1. a - A = 2 - 1 = 1. This condition is satisfied.
  2. z=Z  ⟹  1=1z = Z \implies 1 = 1z=Z⟹1=1. This condition is satisfied. Since both conditions are met, option B is also a valid solution. The reaction is: 49Be+11p→48Be+12D_4^9Be + _1^1p \to _4^8Be + _1^2D49​Be+11​p→48​Be+12​D.

C: (n, D)

  • X is a neutron (01n_0^1n01​n), so A=1 and Z=0.
  • Y is a deuteron (12D_1^2D12​D), so a=2 and z=1.

Check conditions:

  1. a - A = 2 - 1 = 1. This condition is satisfied.
  2. z=Z  ⟹  1=0z = Z \implies 1 = 0z=Z⟹1=0. This is false. Therefore, option C is incorrect. For verification, the reaction 49Be+01n→48Be+12D_4^9Be + _0^1n \to _4^8Be + _1^2D49​Be+01​n→48​Be+12​D shows the atomic number is not conserved (4+0=4 on the left, 4+1=5 on the right).

D: (γ,p)(\gamma ,p)(γ,p)

  • X is a gamma photon (00γ_0^0\gamma00​γ), so A=0 and Z=0.
  • Y is a proton (11p_1^1p11​p), so a=1 and z=1.

Check conditions:

  1. a - A = 1 - 0 = 1. This condition is satisfied.
  2. z=Z  ⟹  1=0z = Z \implies 1 = 0z=Z⟹1=0. This is false. Therefore, option D is incorrect. For verification, the reaction 49Be+00γ→48Be+11p_4^9Be + _0^0\gamma \to _4^8Be + _1^1p49​Be+00​γ→48​Be+11​p shows the atomic number is not conserved (4+0=4 on the left, 4+1=5 on the right).

Conclusion

Based on the analysis, options A and B both satisfy the principles of conservation of mass number and atomic number for the given nuclear transmutation. Thus, both are correct answers.

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