- Athe concentration of the reactant decreases exponentially with time
- Bthe half-life of the reaction decreases with increasing temperature
- Cthe half-life of the reaction depends on the initial concentration of the reactant
- Dthe reaction proceeds to 99.6% completion in eight half-life duration
View written solutionFree
Correct answer: A, B, D
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Identify the key fact:
The reaction is given to be first order.
For a first-order reaction, and the integrated rate law is
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Check Option A:
From the concentration of reactant decreases exponentially with time.
So, A is correct.
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Check Option B:
For a first-order reaction, half-life is
As temperature increases, the rate constant increases according to Arrhenius equation, Hence decreases when temperature increases.
So, B is correct.
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Check Option C:
For a first-order reaction, which is independent of initial concentration.
Therefore, the statement "half-life depends on the initial concentration" is false.
So, C is incorrect.
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Check Option D:
After half-lives, fraction remaining is
For ,
Therefore, fraction completed is
This is approximately completion.
So, D is correct.
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Final answer:
Correct options are:
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Comparison with stored correct answer:
Stored answer: A, B, D
Derived answer: A, B, D
They match.
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