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Chemical Kinetics and Nuclear Chemistry question

2011 · Shift 2 · Q2
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Chemical Kinetics and Nuclear Chemistry question

2011 · Shift 2 · Q2

JEE AdvancedChemistryChemical Kinetics and Nuclear ChemistryMultiple correct+3 / −0.75
For the first order reaction 2N2O5N_2O_5N2​O5​ (g) →\to→ 4NO2NO_2NO2​ (g) + O2O_2O2​ (g)
  1. A
    the concentration of the reactant decreases exponentially with time
  2. B
    the half-life of the reaction decreases with increasing temperature
  3. C
    the half-life of the reaction depends on the initial concentration of the reactant
  4. D
    the reaction proceeds to 99.6% completion in eight half-life duration
View written solutionFree

Correct answer: A, B, D

  1. Identify the key fact:

    The reaction is given to be first order.

    For a first-order reaction, −d[A]dt=k[A]-\frac{d[A]}{dt}=k[A]−dtd[A]​=k[A] and the integrated rate law is [A]t=[A]0e−kt[A]_t=[A]_0 e^{-kt}[A]t​=[A]0​e−kt

  2. Check Option A:

    From [A]t=[A]0e−kt[A]_t=[A]_0 e^{-kt}[A]t​=[A]0​e−kt the concentration of reactant decreases exponentially with time.

    So, A is correct.

  3. Check Option B:

    For a first-order reaction, half-life is t1/2=ln⁡2kt_{1/2}=\frac{\ln 2}{k}t1/2​=kln2​

    As temperature increases, the rate constant kkk increases according to Arrhenius equation, k=Ae−Ea/RTk=Ae^{-E_a/RT}k=Ae−Ea​/RT Hence t1/2t_{1/2}t1/2​ decreases when temperature increases.

    So, B is correct.

  4. Check Option C:

    For a first-order reaction, t1/2=ln⁡2kt_{1/2}=\frac{\ln 2}{k}t1/2​=kln2​ which is independent of initial concentration.

    Therefore, the statement "half-life depends on the initial concentration" is false.

    So, C is incorrect.

  5. Check Option D:

    After nnn half-lives, fraction remaining is (12)n\left(\frac{1}{2}\right)^n(21​)n

    For n=8n=8n=8, fraction remaining=(12)8=1256=0.00390625\text{fraction remaining}=\left(\frac{1}{2}\right)^8=\frac{1}{256}=0.00390625fraction remaining=(21​)8=2561​=0.00390625

    Therefore, fraction completed is 1−0.00390625=0.996093751-0.00390625=0.996093751−0.00390625=0.99609375 =99.609375%=99.609375\%=99.609375%

    This is approximately 99.6%99.6\%99.6% completion.

    So, D is correct.

  6. Final answer:

    Correct options are: A, B, D\boxed{A,\ B,\ D}A, B, D​

  7. Comparison with stored correct answer:

    Stored answer: A, B, D

    Derived answer: A, B, D

    They match.

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