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Chemical Kinetics and Nuclear Chemistry question

2011 · Shift 1 · Q11
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Chemical Kinetics and Nuclear Chemistry question

2011 · Shift 1 · Q11

JEE AdvancedChemistryChemical Kinetics and Nuclear ChemistryMCQ+3 / −1
Bombardment of aluminium by α\alphaα-particle leads to its artificial disintegration in two ways : (i) and (ii) as shown. Products X, Y and Z, respectively, are IIT-JEE 2011 Paper 1 Offline Chemistry - Chemical Kinetics and Nuclear Chemistry Question 9 English
  1. A
    proton, neutron, positron.
  2. B
    neutron, positron, proton.
  3. C
    proton, positron, neutron.
  4. D
    positron, proton, neutron, neutron.
View written solutionFree

Correct answer: A

  1. Identify the known artificial disintegration reactions of aluminium by α\alphaα-particles

Aluminium is 1327Al^{27}_{13}\text{Al}1327​Al and an α\alphaα-particle is 24He^{4}_{2}\text{He}24​He.

So the initial combined nucleus is:

1327Al+24He⇒A=31, Z=15^{27}_{13}\text{Al} + ^{4}_{2}\text{He} \Rightarrow A=31,\ Z=151327​Al+24​He⇒A=31, Z=15

Thus, after bombardment, the products must conserve:

  • Mass number = 313131
  • Atomic number = 151515

  1. First mode of disintegration

A well-known reaction is:

1327Al+24He→1530P+01n^{27}_{13}\text{Al} + ^{4}_{2}\text{He} \rightarrow ^{30}_{15}\text{P} + ^{1}_{0}n1327​Al+24​He→1530​P+01​n

Check conservation:

  • Mass: 27+4=30+1=3127+4=30+1=3127+4=30+1=31
  • Atomic number: 13+2=15+0=1513+2=15+0=1513+2=15+0=15

So in one path, the emitted particle is a neutron.

Hence one of X,Y,ZX, Y, ZX,Y,Z must be neutron.


  1. Second mode of disintegration

Another known reaction is:

1327Al+24He→1430Si+11p^{27}_{13}\text{Al} + ^{4}_{2}\text{He} \rightarrow ^{30}_{14}\text{Si} + ^{1}_{1}p1327​Al+24​He→1430​Si+11​p

Check conservation:

  • Mass: 27+4=30+1=3127+4=30+1=3127+4=30+1=31
  • Atomic number: 13+2=14+1=1513+2=14+1=1513+2=14+1=15

So another emitted particle is a proton.

Thus among X,Y,ZX, Y, ZX,Y,Z, another product is proton.


  1. Formation of positron

The phosphorus formed above, 1530P^{30}_{15}\text{P}1530​P, is radioactive and decays by positron emission:

1530P→1430Si++10e^{30}_{15}\text{P} \rightarrow ^{30}_{14}\text{Si} + ^{0}_{+1}e1530​P→1430​Si++10​e

So the third product is a positron.


  1. Match with options

Thus the three products X,Y,ZX, Y, ZX,Y,Z are:

proton, neutron, positron\text{proton, neutron, positron}proton, neutron, positron

This matches Option A.


  1. Final answer

The correct option is:

A: proton, neutron, positron\boxed{\text{A: proton, neutron, positron}}A: proton, neutron, positron​
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