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Chemical Kinetics and Nuclear Chemistry question

2012 · Shift 1 · Q2
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Chemical Kinetics and Nuclear Chemistry question

2012 · Shift 1 · Q2

JEE AdvancedChemistryChemical Kinetics and Nuclear ChemistryNumerical+3 / −1
The periodic table consists of 18 groups. An isotope of copper, on bombardment with protons undergoes a nuclear reaction yielding element X as shown below. To which group, element X belongs in the periodic table? 2963Cu{}_{29}^{63}Cu2963​Cu+11H→601n{}_1^1H\to6{}_0^1n11​H→601​n+24α{}_2^4\alpha24​α + 2 11H{}_1^1H11​H + X
Numerical answer
View written solutionFree

Correct answer: 8

  1. Write the nuclear reaction

    2963Cu+11H→6 01n+24α+2 11H+X{}_{29}^{63}\mathrm{Cu} + {}_{1}^{1}\mathrm{H} \rightarrow 6\,{}_{0}^{1}\mathrm{n} + {}_{2}^{4}\alpha + 2\,{}_{1}^{1}\mathrm{H} + X2963​Cu+11​H→601​n+24​α+211​H+X

  2. Use conservation of mass number

    Total mass number on LHS: 63+1=6463 + 1 = 6463+1=64

    Total mass number on RHS excluding XXX:

    • 666 neutrons ⇒6×1=6\Rightarrow 6 \times 1 = 6⇒6×1=6
    • one α\alphaα particle ⇒4\Rightarrow 4⇒4
    • 222 protons ⇒2×1=2\Rightarrow 2 \times 1 = 2⇒2×1=2

    So, AX=64−(6+4+2)=64−12=52A_X = 64 - (6+4+2) = 64 - 12 = 52AX​=64−(6+4+2)=64−12=52

    Hence, mass number of XXX is AX=52A_X = 52AX​=52

  3. Use conservation of atomic number

    Total atomic number on LHS: 29+1=3029 + 1 = 3029+1=30

    Total atomic number on RHS excluding XXX:

    • neutrons contribute 000
    • α\alphaα particle contributes 222
    • 222 protons contribute 2×1=22 \times 1 = 22×1=2

    Therefore, ZX=30−(2+2)=30−4=26Z_X = 30 - (2+2) = 30 - 4 = 26ZX​=30−(2+2)=30−4=26

    So element XXX has atomic number ZX=26Z_X = 26ZX​=26

  4. Identify the element

    Atomic number 262626 corresponds to iron (Fe).

  5. Find its group

    Iron belongs to Group 8 of the periodic table.

  6. Final answer

    8\boxed{8}8​

  7. Comparison with stored correct answer

    Stored correct answer = 888

    This matches the derived answer.

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