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Heat and Thermodynamics question

2024 · 4 Apr · Shift 1 · Q74
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Heat and Thermodynamics question

2024 · 4 Apr · Shift 1 · Q74

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
P-T diagram of an ideal gas having three different densities ρ1,ρ2,ρ3\rho_1, \rho_2, \rho_3ρ1​,ρ2​,ρ3​ (in three different cases) is shown in the figure. Which of the following is correct : JEE Main 2024 (Online) 4th April Morning Shift Physics - Heat and Thermodynamics Question 66 English
  1. A
    ρ1>ρ2\rho_1\gt \rho_2ρ1​>ρ2​
  2. B
    ρ2<ρ3\rho_2\lt \rho_3ρ2​<ρ3​
  3. C
    ρ1=ρ2=ρ3\rho_1=\rho_2=\rho_3ρ1​=ρ2​=ρ3​
  4. D
    ρ1<ρ2\rho_1\lt \rho_2ρ1​<ρ2​
View written solutionFree

Correct answer: A

  1. Use the ideal gas equation in density form

For an ideal gas, PV=nRTPV = nRTPV=nRT Also, density is ρ=mV\rho = \frac{m}{V}ρ=Vm​ Using molar mass MMM, we have n=mMn = \frac{m}{M}n=Mm​ So, PV=mMRTPV = \frac{m}{M}RTPV=Mm​RT P=mVRMTP = \frac{m}{V}\frac{R}{M}TP=Vm​MR​T Hence, P=ρRMTP = \rho \frac{R}{M}TP=ρMR​T

Therefore, PT=ρRM\frac{P}{T} = \rho \frac{R}{M}TP​=ρMR​ For the same gas, RRR and MMM are constants, so ρ∝PT\rho \propto \frac{P}{T}ρ∝TP​

  1. Interpret the PPP-TTT graph

In a PPP vs TTT graph, the slope is slope=PT\text{slope} = \frac{P}{T}slope=TP​ Thus, for the same ideal gas, ρ∝slope\rho \propto \text{slope}ρ∝slope So, the line with greater slope corresponds to greater density.

  1. Compare the three lines in the figure

From the given graph, the line corresponding to ρ1\rho_1ρ1​ is steeper than the line corresponding to ρ2\rho_2ρ2​. Hence, ρ1>ρ2\rho_1 > \rho_2ρ1​>ρ2​

Also, the three slopes are not equal, so ρ1=ρ2=ρ3\rho_1 = \rho_2 = \rho_3ρ1​=ρ2​=ρ3​ is false.

  1. Check options
  • A: ρ1>ρ2\rho_1 > \rho_2ρ1​>ρ2​ ✅
  • B: ρ2<ρ3\rho_2 < \rho_3ρ2​<ρ3​ — not the correct relation from the graph
  • C: ρ1=ρ2=ρ3\rho_1 = \rho_2 = \rho_3ρ1​=ρ2​=ρ3​ ❌
  • D: ρ1<ρ2\rho_1 < \rho_2ρ1​<ρ2​ ❌
  1. Final answer

The correct option is: A\boxed{A}A​

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