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Heat and Thermodynamics question

2024 · 1 Feb · Shift 2 · Q74
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Heat and Thermodynamics question

2024 · 1 Feb · Shift 2 · Q74

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
If the root mean square velocity of hydrogen molecule at a given temperature and pressure is 2 km/s2 \mathrm{~km} / \mathrm{s}2 km/s, the root mean square velocity of oxygen at the same condition in km/s\mathrm{km} / \mathrm{s}km/s is :
  1. A
    1.0
  2. B
    1.5
  3. C
    2.0
  4. D
    0.5
View written solutionFree

Correct answer: D

  1. Use the formula for RMS speed

For a gas, the root mean square speed is

vrms=3RTMv_{\mathrm{rms}} = \sqrt{\frac{3RT}{M}}vrms​=M3RT​​

where:

  • RRR is the gas constant,
  • TTT is the absolute temperature,
  • MMM is the molar mass.

At the same temperature, we have

vrms∝1Mv_{\mathrm{rms}} \propto \frac{1}{\sqrt{M}}vrms​∝M​1​

  1. Compare hydrogen and oxygen

For hydrogen gas H2\mathrm{H_2}H2​:

MH2=2M_{\mathrm{H_2}} = 2MH2​​=2

For oxygen gas O2\mathrm{O_2}O2​:

MO2=32M_{\mathrm{O_2}} = 32MO2​​=32

Therefore,

vO2vH2=MH2MO2=232=116=14\frac{v_{\mathrm{O_2}}}{v_{\mathrm{H_2}}} = \sqrt{\frac{M_{\mathrm{H_2}}}{M_{\mathrm{O_2}}}} = \sqrt{\frac{2}{32}} = \sqrt{\frac{1}{16}} = \frac{1}{4}vH2​​vO2​​​=MO2​​MH2​​​​=322​​=161​​=41​

  1. Substitute the given speed

Given:

vH2=2 km/sv_{\mathrm{H_2}} = 2\ \text{km/s}vH2​​=2 km/s

So,

vO2=2×14=0.5 km/sv_{\mathrm{O_2}} = 2 \times \frac{1}{4} = 0.5\ \text{km/s}vO2​​=2×41​=0.5 km/s

  1. Match with the options

0.5 km/s0.5\ \text{km/s}0.5 km/s

So the correct option is:

D: 0.5

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