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Heat and Thermodynamics question

2020 · 7 Jan · Shift 2 · Q45
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Heat and Thermodynamics question

2020 · 7 Jan · Shift 2 · Q45

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
Under an adiabatic process, the volume of an ideal gas gets doubled. Consequently the mean collision time between the gas molecule changes from τ1{\tau _1}τ1​ to τ2{\tau _2}τ2​. If CpCv=γ{{{C_p}} \over {{C_v}}} = \gammaCv​Cp​​=γ for this gas then a good estimate for τ2τ1{{{\tau _2}} \over {{\tau _1}}}τ1​τ2​​ is given by :
  1. A
    (2)1+γ2{\left( 2 \right)^{{{1 + \gamma } \over 2}}}(2)21+γ​
  2. B
    2
  3. C
    (12)1+γ2{\left( {{1 \over 2}} \right)^{{{1 + \gamma } \over 2}}}(21​)21+γ​
  4. D
    (12)γ{\left( {{1 \over 2}} \right)^\gamma }(21​)γ
View written solutionFree

Correct answer: A

  1. Use adiabatic relation

For an ideal gas in an adiabatic process, PVγ=constantPV^\gamma=\text{constant}PVγ=constant Also, using PV=nRTPV=nRTPV=nRT, TVγ−1=constantTV^{\gamma-1}=\text{constant}TVγ−1=constant

Given the volume doubles: V2=2V1V_2=2V_1V2​=2V1​ So, T1V1γ−1=T2V2γ−1T_1V_1^{\gamma-1}=T_2V_2^{\gamma-1}T1​V1γ−1​=T2​V2γ−1​ ⇒T2T1=(V1V2)γ−1=(12)γ−1\Rightarrow \frac{T_2}{T_1}=\left(\frac{V_1}{V_2}\right)^{\gamma-1}=\left(\frac{1}{2}\right)^{\gamma-1}⇒T1​T2​​=(V2​V1​​)γ−1=(21​)γ−1

  1. Relate mean collision time to temperature and volume

Mean collision time can be estimated as τ∼λvˉ\tau \sim \frac{\lambda}{\bar v}τ∼vˉλ​ where λ\lambdaλ is mean free path and vˉ\bar vvˉ is average molecular speed.

For an ideal gas,

  • Mean free path: λ∝1n∝V\lambda \propto \frac{1}{n} \propto Vλ∝n1​∝V (since number of molecules is fixed, n∝1/Vn \propto 1/Vn∝1/V)

  • Average speed: vˉ∝T\bar v \propto \sqrt{T}vˉ∝T​

Hence, τ∝VT\tau \propto \frac{V}{\sqrt{T}}τ∝T​V​

Therefore, τ2τ1=V2V1T1T2\frac{\tau_2}{\tau_1}=\frac{V_2}{V_1}\sqrt{\frac{T_1}{T_2}}τ1​τ2​​=V1​V2​​T2​T1​​​

  1. Substitute the adiabatic temperature change

We have V2V1=2\frac{V_2}{V_1}=2V1​V2​​=2 and T1T2=2γ−1\frac{T_1}{T_2}=2^{\gamma-1}T2​T1​​=2γ−1 Thus, τ2τ1=22γ−1\frac{\tau_2}{\tau_1}=2\sqrt{2^{\gamma-1}}τ1​τ2​​=22γ−1​ =2⋅2(γ−1)/2=2\cdot 2^{(\gamma-1)/2}=2⋅2(γ−1)/2 =21+(γ−1)/2=2^{1+(\gamma-1)/2}=21+(γ−1)/2 =2(1+γ)/2=2^{(1+\gamma)/2}=2(1+γ)/2

  1. Match with options

τ2τ1=21+γ2\frac{\tau_2}{\tau_1}=2^{\frac{1+\gamma}{2}}τ1​τ2​​=221+γ​ This corresponds to Option A.

  1. Comparison with stored answer

Stored correct answer: A

Our derived answer also gives A, so they agree.

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