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Heat and Thermodynamics question

2020 · 8 Jan · Shift 1 · Q63
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Heat and Thermodynamics question

2020 · 8 Jan · Shift 1 · Q63

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
The plot that depicts the behavior of the mean free time t (time between two successive collisions) for the molecules of an ideal gas, as a function of temperature (T), qualitatively, is: (Graphs are schematic and not drawn to scale)
  1. A
    JEE Main 2020 (Online) 8th January Morning Slot Physics - Heat and Thermodynamics Question 314 English Option 1
  2. B
    JEE Main 2020 (Online) 8th January Morning Slot Physics - Heat and Thermodynamics Question 314 English Option 2
  3. C
    JEE Main 2020 (Online) 8th January Morning Slot Physics - Heat and Thermodynamics Question 314 English Option 3
  4. D
    JEE Main 2020 (Online) 8th January Morning Slot Physics - Heat and Thermodynamics Question 314 English Option 4
View written solutionFree

Correct answer: B

  1. For an ideal gas, the mean free time ttt between successive collisions is t=λvˉt=\frac{\lambda}{\bar v}t=vˉλ​ where λ\lambdaλ is the mean free path and vˉ\bar vvˉ is the average molecular speed.

  2. For an ideal gas, λ=12 πd2n\lambda=\frac{1}{\sqrt{2}\,\pi d^2 n}λ=2​πd2n1​ where ddd is molecular diameter and nnn is number density.

  3. Since the question asks dependence on temperature TTT, we take the usual case of a fixed amount of gas at constant pressure unless otherwise implied.

Using ideal gas law, n=NV=PkTn=\frac{N}{V}=\frac{P}{kT}n=VN​=kTP​ So, λ∝1n∝T\lambda \propto \frac{1}{n}\propto Tλ∝n1​∝T (at constant pressure).

  1. Average molecular speed varies as vˉ∝T\bar v \propto \sqrt{T}vˉ∝T​

  2. Therefore, t=λvˉ∝TT=Tt=\frac{\lambda}{\bar v}\propto \frac{T}{\sqrt{T}}=\sqrt{T}t=vˉλ​∝T​T​=T​ So mean free time increases with temperature, but not linearly; it rises like T\sqrt{T}T​, i.e. an increasing curve with decreasing slope (concave downward).

  3. Hence the correct qualitative graph is the one representing

  • ttt increasing with TTT
  • with slope gradually decreasing.

That corresponds to Option B.

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