JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
The plot that depicts the behavior of the mean free time t (time between two successive collisions) for the molecules of an ideal gas, as a function of temperature (T), qualitatively, is: (Graphs are schematic and not drawn to scale)
- A

- B

- C

- D

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Correct answer: B
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For an ideal gas, the mean free time between successive collisions is where is the mean free path and is the average molecular speed.
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For an ideal gas, where is molecular diameter and is number density.
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Since the question asks dependence on temperature , we take the usual case of a fixed amount of gas at constant pressure unless otherwise implied.
Using ideal gas law, So, (at constant pressure).
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Average molecular speed varies as
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Therefore, So mean free time increases with temperature, but not linearly; it rises like , i.e. an increasing curve with decreasing slope (concave downward).
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Hence the correct qualitative graph is the one representing
- increasing with
- with slope gradually decreasing.
That corresponds to Option B.
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