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Heat and Thermodynamics question

2020 · 4 Sep · Shift 1 · Q63
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Heat and Thermodynamics question

2020 · 4 Sep · Shift 1 · Q63

JEE MainPhysicsHeat and ThermodynamicsNumerical+4 / −1
A closed vessel contains 0.1 mole of a monoatomic ideal gas at 200 K. If 0.05 mole of the same gas at 400 K is added to it, the final equilibrium temperature (in K) of the gas in the vessel will be close to ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 267

  1. Given data
  • Initial gas in vessel: n1=0.1 mol,T1=200 Kn_1 = 0.1\ \text{mol}, \quad T_1 = 200\ \text{K}n1​=0.1 mol,T1​=200 K
  • Added gas: n2=0.05 mol,T2=400 Kn_2 = 0.05\ \text{mol}, \quad T_2 = 400\ \text{K}n2​=0.05 mol,T2​=400 K
  • Both are the same monoatomic ideal gas.
  1. Physical idea

Since the vessel is closed and we are mixing the same ideal gas, the final equilibrium temperature is found by conservation of internal energy.

For a monoatomic ideal gas, U=nCVTU = n C_V TU=nCV​T with CV=3R2C_V = \frac{3R}{2}CV​=23R​ which is the same for both samples.

So, n1CVT1+n2CVT2=(n1+n2)CVTfn_1 C_V T_1 + n_2 C_V T_2 = (n_1+n_2) C_V T_fn1​CV​T1​+n2​CV​T2​=(n1​+n2​)CV​Tf​

Cancelling CVC_VCV​: n1T1+n2T2=(n1+n2)Tfn_1 T_1 + n_2 T_2 = (n_1+n_2) T_fn1​T1​+n2​T2​=(n1​+n2​)Tf​

  1. Substitute values

Tf=n1T1+n2T2n1+n2T_f = \frac{n_1 T_1 + n_2 T_2}{n_1+n_2}Tf​=n1​+n2​n1​T1​+n2​T2​​

Tf=(0.1)(200)+(0.05)(400)0.1+0.05T_f = \frac{(0.1)(200) + (0.05)(400)}{0.1+0.05}Tf​=0.1+0.05(0.1)(200)+(0.05)(400)​

Tf=20+200.15T_f = \frac{20 + 20}{0.15}Tf​=0.1520+20​

Tf=400.15=266.67 KT_f = \frac{40}{0.15} = 266.67\ \text{K}Tf​=0.1540​=266.67 K

  1. Final integer value

The temperature is close to 267 K\boxed{267\ \text{K}}267 K​

  1. Comparison with stored answer

Stored correct answer: 266266266

Our calculated value is 266.67 K266.67\,\text{K}266.67K, which is closer to 267267267 than 266266266. So I disagree with the stored answer if the question expects the nearest integer.

If the exam intended truncation or simply “close to”, then 266266266 may have been accepted, but mathematically the nearest integer is 267267267.

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