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Atoms and Nuclei question

2025 · 4 Apr · Shift 1 · Q60
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Atoms and Nuclei question

2025 · 4 Apr · Shift 1 · Q60

JEE MainPhysicsAtoms and NucleiMCQ+4 / −1
Considering the Bohr model of hydrogen like atoms, the ratio of the radius of 5th 5^{\text {th }}5th  orbit of the electron in Li2+\mathrm{Li}^{2+}Li2+ and He+\mathrm{He}^{+}He+ is
  1. A
    32\frac{3}{2}23​
  2. B
    23\frac{2}{3}32​
  3. C
    49\frac{4}{9}94​
  4. D
    94\frac{9}{4}49​
View written solutionFree

Correct answer: B

  1. Bohr radius formula for hydrogen-like atoms

For a hydrogen-like ion, the radius of the nthn^{\text{th}}nth orbit is

rn=n2a0Zr_n = \frac{n^2 a_0}{Z}rn​=Zn2a0​​

where:

  • nnn = principal quantum number
  • a0a_0a0​ = Bohr radius
  • ZZZ = atomic number
  1. Write the radius for each ion in the 5th5^{\text{th}}5th orbit

Since both are in the 5th5^{\text{th}}5th orbit, n=5n=5n=5 for both.

  • For Li2+\mathrm{Li}^{2+}Li2+, Z=3Z=3Z=3
rLi2+=52a03=25a03r_{\mathrm{Li}^{2+}} = \frac{5^2 a_0}{3} = \frac{25a_0}{3}rLi2+​=352a0​​=325a0​​
  • For He+\mathrm{He}^{+}He+, Z=2Z=2Z=2
rHe+=52a02=25a02r_{\mathrm{He}^{+}} = \frac{5^2 a_0}{2} = \frac{25a_0}{2}rHe+​=252a0​​=225a0​​
  1. Find the required ratio
rLi2+rHe+=25a0325a02=25a03⋅225a0=23\frac{r_{\mathrm{Li}^{2+}}}{r_{\mathrm{He}^{+}}} = \frac{\frac{25a_0}{3}}{\frac{25a_0}{2}} = \frac{25a_0}{3} \cdot \frac{2}{25a_0} = \frac{2}{3}rHe+​rLi2+​​=225a0​​325a0​​​=325a0​​⋅25a0​2​=32​
  1. Match with the options
23\frac{2}{3}32​

So the correct option is B.

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