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Atoms and Nuclei question

2022 · 25 Jul · Shift 2 · Q62
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  5. /2022 · 25 Jul · Shift 2 · Q62

Atoms and Nuclei question

2022 · 25 Jul · Shift 2 · Q62

JEE MainPhysicsAtoms and NucleiMCQ+4 / −1
Hydrogen atom from excited state comes to the ground state by emitting a photon of wavelength λ\lambdaλ. The value of principal quantum number 'nnn' of the excited state will be : (R:\mathrm{R}:R: Rydberg constant)
  1. A
    λRλ−1\sqrt{\frac{\lambda \mathrm{R}}{\lambda-1}}λ−1λR​​
  2. B
    λRλR−1\sqrt{\frac{\lambda \mathrm{R}}{\lambda \mathrm{R}-1}}λR−1λR​​
  3. C
    λλR−1\sqrt{\frac{\lambda}{\lambda \mathrm{R}-1}}λR−1λ​​
  4. D
    λR2λR−1\sqrt{\frac{\lambda R^{2}}{\lambda R-1}}λR−1λR2​​
View written solutionFree

Correct answer: B

  1. Use the Rydberg formula for hydrogen

When an electron in hydrogen falls from an excited state nnn to the ground state 111, the emitted photon wavelength λ\lambdaλ satisfies

1λ=R(112−1n2)\frac{1}{\lambda}=R\left(\frac{1}{1^2}-\frac{1}{n^2}\right)λ1​=R(121​−n21​)

So,

1λ=R(1−1n2)\frac{1}{\lambda}=R\left(1-\frac{1}{n^2}\right)λ1​=R(1−n21​)
  1. Rearrange to solve for nnn

Divide by RRR:

1λR=1−1n2\frac{1}{\lambda R}=1-\frac{1}{n^2}λR1​=1−n21​

Hence,

1n2=1−1λR\frac{1}{n^2}=1-\frac{1}{\lambda R}n21​=1−λR1​

Take LCM:

1n2=λR−1λR\frac{1}{n^2}=\frac{\lambda R-1}{\lambda R}n21​=λRλR−1​

Therefore,

n2=λRλR−1n^2=\frac{\lambda R}{\lambda R-1}n2=λR−1λR​

and

n=λRλR−1n=\sqrt{\frac{\lambda R}{\lambda R-1}}n=λR−1λR​​
  1. Match with the options

This matches Option B:

λRλR−1\sqrt{\frac{\lambda R}{\lambda R-1}}λR−1λR​​
  1. Check other options briefly
  • A: λRλ−1\sqrt{\frac{\lambda R}{\lambda-1}}λ−1λR​​ has inconsistent form.
  • C: λλR−1\sqrt{\frac{\lambda}{\lambda R-1}}λR−1λ​​ misses a factor of RRR in the numerator.
  • D: λR2λR−1\sqrt{\frac{\lambda R^2}{\lambda R-1}}λR−1λR2​​ has an extra factor of RRR.

So only B is correct.

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