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Atoms and Nuclei question

2019 · 11 Jan · Shift 2 · Q60
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Atoms and Nuclei question

2019 · 11 Jan · Shift 2 · Q60

JEE MainPhysicsAtoms and NucleiMCQ+4 / −1
In a hydrogen like atom, when an electron jumps from the M-shell to the L-shell, the wavelength of emitted radiation is λ\lambdaλ. If an electron jumps from N-shell to the L-shell, the wavelength of emitted radiation will be:
  1. A
    2516λ{{25} \over {16}}\lambda1625​λ
  2. B
    2720λ{{27} \over {20}}\lambda2027​λ
  3. C
    1625λ{{16} \over {25}}\lambda2516​λ
  4. D
    2027λ{{20} \over {27}}\lambda2720​λ
View written solutionFree

Correct answer: D

  1. Use the Rydberg formula for a hydrogen-like atom

For emission from level n2n_2n2​ to n1n_1n1​,

1λ=RZ2(1n12−1n22)\frac{1}{\lambda} = R Z^2 \left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right)λ1​=RZ2(n12​1​−n22​1​)

where RRR is the Rydberg constant and ZZZ is the atomic number.

  1. Transition from M-shell to L-shell

Here,

  • M-shell ⇒n2=3\Rightarrow n_2 = 3⇒n2​=3
  • L-shell ⇒n1=2\Rightarrow n_1 = 2⇒n1​=2

So,

1λ=RZ2(122−132)\frac{1}{\lambda} = RZ^2\left(\frac{1}{2^2} - \frac{1}{3^2}\right)λ1​=RZ2(221​−321​)

1λ=RZ2(14−19)=RZ2(536)\frac{1}{\lambda} = RZ^2\left(\frac{1}{4} - \frac{1}{9}\right) = RZ^2\left(\frac{5}{36}\right)λ1​=RZ2(41​−91​)=RZ2(365​)

Thus,

λ=365RZ2\lambda = \frac{36}{5RZ^2}λ=5RZ236​

  1. Transition from N-shell to L-shell

Here,

  • N-shell ⇒n2=4\Rightarrow n_2 = 4⇒n2​=4
  • L-shell ⇒n1=2\Rightarrow n_1 = 2⇒n1​=2

Let the new wavelength be λ′\lambda'λ′.

1λ′=RZ2(122−142)\frac{1}{\lambda'} = RZ^2\left(\frac{1}{2^2} - \frac{1}{4^2}\right)λ′1​=RZ2(221​−421​)

1λ′=RZ2(14−116)=RZ2(316)\frac{1}{\lambda'} = RZ^2\left(\frac{1}{4} - \frac{1}{16}\right) = RZ^2\left(\frac{3}{16}\right)λ′1​=RZ2(41​−161​)=RZ2(163​)

So,

λ′=163RZ2\lambda' = \frac{16}{3RZ^2}λ′=3RZ216​

  1. Find the ratio λ′/λ\lambda'/\lambdaλ′/λ

λ′λ=163RZ2365RZ2\frac{\lambda'}{\lambda} = \frac{\frac{16}{3RZ^2}}{\frac{36}{5RZ^2}}λλ′​=5RZ236​3RZ216​​

λ′λ=163⋅536=80108=2027\frac{\lambda'}{\lambda} = \frac{16}{3} \cdot \frac{5}{36} = \frac{80}{108} = \frac{20}{27}λλ′​=316​⋅365​=10880​=2720​

Hence,

λ′=2027λ\lambda' = \frac{20}{27}\lambdaλ′=2720​λ

  1. Match with the options

The correct option is:

D: 2027λ\dfrac{20}{27}\lambda2720​λ

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