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Atoms and Nuclei question

2018 · 15 Apr · Shift 1 · Q56
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Atoms and Nuclei question

2018 · 15 Apr · Shift 1 · Q56

JEE MainPhysicsAtoms and NucleiMCQ+4 / −1
The energy required to remove the electron from a singly ionized Helium atom is 2.22.22.2 times the energies required to remove an electron from Helium atom. The total energy required to ionize the Helium atom completely is :
  1. A
    20eV20eV20eV
  2. B
    34eV34eV34eV
  3. C
    79eV79eV79eV
  4. D
    109eV109eV109eV
View written solutionFree

Correct answer: C

  1. Let the first ionization energy of helium be E1E_1E1​.

    This is the energy required to remove one electron from a neutral helium atom: He→He++e−\text{He} \to \text{He}^+ + e^-He→He++e−

  2. Given relation for singly ionized helium

    The energy required to remove the electron from He+\text{He}^+He+ is 2.22.22.2 times the energy required to remove an electron from He atom.

    So, if the second ionization energy is E2E_2E2​, then E2=2.2E1E_2 = 2.2E_1E2​=2.2E1​

  3. Use hydrogen-like atom formula for He+\text{He}^+He+

    A singly ionized helium atom He+\text{He}^+He+ is a hydrogen-like ion with atomic number Z=2Z=2Z=2.

    Its ground state ionization energy is E2=13.6Z2=13.6×22=54.4 eVE_2 = 13.6 Z^2 = 13.6 \times 2^2 = 54.4\,\text{eV}E2​=13.6Z2=13.6×22=54.4eV

  4. Find the first ionization energy

    From 54.4=2.2E154.4 = 2.2E_154.4=2.2E1​ we get E1=54.42.2E_1 = \frac{54.4}{2.2}E1​=2.254.4​ E1≈24.73 eVE_1 \approx 24.73\,\text{eV}E1​≈24.73eV

  5. Total energy to ionize helium completely

    This is the sum of first and second ionization energies: Etotal=E1+E2E_{\text{total}} = E_1 + E_2Etotal​=E1​+E2​ Etotal=24.73+54.4=79.13 eVE_{\text{total}} = 24.73 + 54.4 = 79.13\,\text{eV}Etotal​=24.73+54.4=79.13eV

  6. Match with options

    Etotal≈79 eVE_{\text{total}} \approx 79\,\text{eV}Etotal​≈79eV

    Therefore, the correct option is C.

  7. Comparison with stored answer

    Stored correct answer: C

    My derived answer: C

    Hence, they agree.

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