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Atoms and Nuclei question

2019 · 11 Jan · Shift 1 · Q65
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Atoms and Nuclei question

2019 · 11 Jan · Shift 1 · Q65

JEE MainPhysicsAtoms and NucleiMCQ+4 / −1
A hydrogen atom, initially in the ground state is excited by absorbing a photon of wavelength 980 A∘\mathop A\limits^ \circA∘​. The radius of the atom in the excited state, in terms of Bohr radius a0 will be : (hc = 12500 eV A∘\mathop A\limits^ \circA∘​)
  1. A
    4a0
  2. B
    9a0
  3. C
    25a0
  4. D
    16a0
View written solutionFree

Correct answer: D

  1. Energy of the absorbed photon

Given wavelength, λ=980 A˚\lambda = 980\,\text{\AA}λ=980A˚

Using E=hcλE = \frac{hc}{\lambda}E=λhc​ with hc=12500 eVA˚hc = 12500\,\text{eV\AA}hc=12500eVA˚ we get E=12500980 eVE = \frac{12500}{980}\,\text{eV}E=98012500​eV E≈12.76 eVE \approx 12.76\,\text{eV}E≈12.76eV

  1. Energy needed to excite hydrogen from ground state

For hydrogen atom, En=−13.6n2 eVE_n = -\frac{13.6}{n^2}\,\text{eV}En​=−n213.6​eV

Initially the atom is in ground state, so E1=−13.6 eVE_1 = -13.6\,\text{eV}E1​=−13.6eV

If it absorbs a photon and reaches level nnn, then Ephoton=En−E1E_{\text{photon}} = E_n - E_1Ephoton​=En​−E1​

So, 12.76=−13.6n2−(−13.6)12.76 = -\frac{13.6}{n^2} - (-13.6)12.76=−n213.6​−(−13.6) 12.76=13.6(1−1n2)12.76 = 13.6\left(1 - \frac{1}{n^2}\right)12.76=13.6(1−n21​)

Divide by 13.613.613.6: 12.7613.6=1−1n2\frac{12.76}{13.6} = 1 - \frac{1}{n^2}13.612.76​=1−n21​ 0.938≈1−1n20.938 \approx 1 - \frac{1}{n^2}0.938≈1−n21​

Thus, 1n2≈0.062=116\frac{1}{n^2} \approx 0.062 = \frac{1}{16}n21​≈0.062=161​

Hence, n2=16⇒n=4n^2 = 16 \Rightarrow n=4n2=16⇒n=4

  1. Radius of hydrogen atom in nth orbit

Bohr radius formula: rn=n2a0r_n = n^2 a_0rn​=n2a0​

For n=4n=4n=4, r4=42a0=16a0r_4 = 4^2 a_0 = 16a_0r4​=42a0​=16a0​

  1. Option check
  • A: 4a04a_04a0​ ❌
  • B: 9a09a_09a0​ ❌
  • C: 25a025a_025a0​ ❌
  • D: 16a016a_016a0​ ✅

Therefore, the correct answer is D.

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