JEE MainChemistryThermodynamicsNumerical+4 / −1
The reaction of cyanamide, (s) with oxygen was run in a bomb calorimeter and U was found to be 742.24 kJ mol 1. The magnitude of H298 for the reaction is kJ. (Rounded off to the nearest integer) [Assume ideal gases and R = 8.314 J mol 1 K 1]
Numerical answer
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Correct answer: 741
- Given data
- For the combustion reaction in a bomb calorimeter:
- Temperature:
- Gas constant:
We need the magnitude of .
- Use the relation between and
For ideal gases, where is the change in moles of gaseous species.
- Find from the given reaction
The reaction is written as:
Count gaseous moles:
- Reactant gases =
- Product gases =
So,
- Calculate
- Calculate
Thus, the magnitude is
Rounded to nearest integer:
- Comparison with stored answer
Stored correct answer =
Our derived answer also gives , so they agree.
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