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Correct answer: 3
- Given data
- Number of moles:
- Temperature:
- Initial pressure:
- Final pressure:
- Gas is ideal and the process is isothermal
- External pressure given as
We need heat transferred per mole in kJ mol.
- Use first law of thermodynamics
For an ideal gas in an isothermal process,
So,
Hence we first calculate the work.
- Work done against constant external pressure
For an irreversible expansion/compression against constant external pressure,
Now for an ideal gas at constant temperature,
So,
Thus,
Therefore,
- Substitute values
First calculate :
Now,
Using MPa consistently,
So,
Now multiply by :
Hence,
So,
for 5 moles.
- Heat per mole
Rounded to nearest integer:
- Check physical consistency
The problem says the gas is expanded from to . For expansion, the external pressure should normally be less than the gas pressure, but is greater than both given pressures. That is physically inconsistent with expansion. This strongly suggests a likely misprint in the question, possibly the external pressure should be much smaller.
If one incorrectly uses the reversible isothermal formula,
then
Per mole,
which is still not .
So the stored answer does not match the given data under standard thermodynamic interpretation.
- Conclusion
Using the given data and the stated constant external pressure process,
(rounded to nearest integer).
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