Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Thermodynamics question

2021 · 25 Feb · Shift 2 · Q20
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Thermodynamics
  5. /2021 · 25 Feb · Shift 2 · Q20

Thermodynamics question

2021 · 25 Feb · Shift 2 · Q20

JEE MainChemistryThermodynamicsNumerical+4 / −1
Five moles of an ideal gas at 293 K is expanded isothermally from an initial pressure of 2.1 MPa to 1.3 MPa against at constant external pressure 4.3 MPa. The heat transferred in this process is ‾\underline{\hspace{2cm}}​ kJ mol −-− 1. (Rounded off to the nearest integer) [Use R = 8.314 J mol −-− 1K −-− 1]
Numerical answer
View written solutionFree

Correct answer: 3

  1. Given data
  • Number of moles: n=5n = 5n=5
  • Temperature: T=293 KT = 293\,\text{K}T=293K
  • Initial pressure: P1=2.1 MPaP_1 = 2.1\,\text{MPa}P1​=2.1MPa
  • Final pressure: P2=1.3 MPaP_2 = 1.3\,\text{MPa}P2​=1.3MPa
  • Gas is ideal and the process is isothermal
  • External pressure given as 4.3 MPa4.3\,\text{MPa}4.3MPa
  • R=8.314 J mol−1K−1R = 8.314\,\text{J mol}^{-1}\text{K}^{-1}R=8.314J mol−1K−1

We need heat transferred per mole in kJ mol−1^{-1}−1.


  1. Use first law of thermodynamics

For an ideal gas in an isothermal process,

ΔU=0\Delta U = 0ΔU=0

So,

q=−wq = -wq=−w

Hence we first calculate the work.


  1. Work done against constant external pressure

For an irreversible expansion/compression against constant external pressure,

w=−Pext(V2−V1)w = -P_{\text{ext}}(V_2 - V_1)w=−Pext​(V2​−V1​)

Now for an ideal gas at constant temperature,

V=nRTPV = \frac{nRT}{P}V=PnRT​

So,

V1=nRTP1,V2=nRTP2V_1 = \frac{nRT}{P_1}, \qquad V_2 = \frac{nRT}{P_2}V1​=P1​nRT​,V2​=P2​nRT​

Thus,

V2−V1=nRT(1P2−1P1)V_2 - V_1 = nRT\left(\frac{1}{P_2} - \frac{1}{P_1}\right)V2​−V1​=nRT(P2​1​−P1​1​)

Therefore,

w=−Pext nRT(1P2−1P1)w = -P_{\text{ext}}\,nRT\left(\frac{1}{P_2} - \frac{1}{P_1}\right)w=−Pext​nRT(P2​1​−P1​1​)


  1. Substitute values

First calculate nRTnRTnRT:

nRT=5×8.314×293=12179.01 JnRT = 5 \times 8.314 \times 293 = 12179.01\,\text{J}nRT=5×8.314×293=12179.01J

Now,

1P2−1P1=11.3−12.1\frac{1}{P_2} - \frac{1}{P_1} = \frac{1}{1.3} - \frac{1}{2.1}P2​1​−P1​1​=1.31​−2.11​

Using MPa consistently,

11.3≈0.76923,12.1≈0.47619\frac{1}{1.3} \approx 0.76923, \qquad \frac{1}{2.1} \approx 0.476191.31​≈0.76923,2.11​≈0.47619

So,

1P2−1P1≈0.29304 MPa−1\frac{1}{P_2} - \frac{1}{P_1} \approx 0.29304\,\text{MPa}^{-1}P2​1​−P1​1​≈0.29304MPa−1

Now multiply by Pext=4.3 MPaP_{\text{ext}} = 4.3\,\text{MPa}Pext​=4.3MPa:

Pext(1P2−1P1)=4.3×0.29304≈1.2601P_{\text{ext}}\left(\frac{1}{P_2} - \frac{1}{P_1}\right) = 4.3 \times 0.29304 \approx 1.2601Pext​(P2​1​−P1​1​)=4.3×0.29304≈1.2601

Hence,

w=−12179.01×1.2601≈−15345 Jw = -12179.01 \times 1.2601 \approx -15345\,\text{J}w=−12179.01×1.2601≈−15345J

So,

q=−w≈+15345 Jq = -w \approx +15345\,\text{J}q=−w≈+15345J

for 5 moles.


  1. Heat per mole

qper mole=153455≈3069 J mol−1q_{\text{per mole}} = \frac{15345}{5} \approx 3069\,\text{J mol}^{-1}qper mole​=515345​≈3069J mol−1

qper mole≈3.07 kJ mol−1q_{\text{per mole}} \approx 3.07\,\text{kJ mol}^{-1}qper mole​≈3.07kJ mol−1

Rounded to nearest integer:

3\boxed{3}3​


  1. Check physical consistency

The problem says the gas is expanded from 2.1 MPa2.1\,\text{MPa}2.1MPa to 1.3 MPa1.3\,\text{MPa}1.3MPa. For expansion, the external pressure should normally be less than the gas pressure, but 4.3 MPa4.3\,\text{MPa}4.3MPa is greater than both given pressures. That is physically inconsistent with expansion. This strongly suggests a likely misprint in the question, possibly the external pressure should be much smaller.

If one incorrectly uses the reversible isothermal formula,

q=nRTln⁡P1P2q = nRT\ln\frac{P_1}{P_2}q=nRTlnP2​P1​​

then

q=5×8.314×293×ln⁡(2.11.3)≈5844 Jq = 5\times 8.314\times 293\times \ln\left(\frac{2.1}{1.3}\right) \approx 5844\,\text{J}q=5×8.314×293×ln(1.32.1​)≈5844J

Per mole,

≈1.17 kJ mol−1\approx 1.17\,\text{kJ mol}^{-1}≈1.17kJ mol−1

which is still not 151515.

So the stored answer does not match the given data under standard thermodynamic interpretation.


  1. Conclusion

Using the given data and the stated constant external pressure process,

q=3 kJ mol−1\boxed{q = 3\,\text{kJ mol}^{-1}}q=3kJ mol−1​

(rounded to nearest integer).

PreviousNext

More from Thermodynamics

  • At 298 K, the enthalpy of fusion of a solid (X) is 2.8 kJ mol − 1 and the enthalpy of vaporisation of the liquid (X) is 98.2 kJ mol − 1. The enthalpy of sublimation of the substance (X) in kJ mol − 1 is ​.…2021 · Numerical
  • A system does 200 J of work and at the same time absorbs 150 J of heat. The magnitude of the change in internal energy is ​ J. (Nearest integer)2021 · Numerical
  • The Born-Haber cycle for KCl is evaluated with the following data : Δf​HΘ for KCl =− 436.7 kJ mol − 1 ; Δsub​HΘ for K = 89.2 kJ mol − 1 ; Δionization​HΘ for K = 419.0…2021 · Numerical
  • For water Δ vap H = 41 kJ mol − 1 at 373 K and 1 bar pressure. Assuming that water vapour is an ideal gas that occupies a much larger volume than liquid water, the internal energy change during evaporation of water is ​…2021 · Numerical
  • For a chemical reaction A + B ⇌ C + D (Δr​HΘ = 80 kJ mol − 1) the entropy change Δr​SΘ depends on the temperature T (in K) as Δr​SΘ = 2T (J K − 1mol − 1). Minimum temperature…2021 · Numerical
  • An exothermic reaction X → Y has an activation energy 30 kJ mol − 1. If energy change Δ E during the reaction is − 20 kJ, then the activation energy for the reverse reaction in kJ is ​. (Integer…2021 · Numerical
  • The average S-F bond energy in kJ mol − 1 of SF6​ is ​. (Rounded off to the nearest integer) [Given : The values of standard enthalpy of formation of SF6​(g), S(g) and F(g) are - 1100, 275 and 80 kJ mol − 1…2021 · Numerical
  • 200 mL of 0.2 M HCl is mixed with 300 mL of 0.1 M NaOH. The molar heat of neutralization of this reaction is − 57.1 kJ. The increase in temperature in ∘ C of the system on mixing is x × 10 − 2. The value of x is ​…2021 · Numerical