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Thermodynamics question

2021 · 24 Feb · Shift 2 · Q18
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  5. /2021 · 24 Feb · Shift 2 · Q18

Thermodynamics question

2021 · 24 Feb · Shift 2 · Q18

JEE MainChemistryThermodynamicsNumerical+4 / −1
Assuming ideal behaviour, the magnitude of log K for the following reaction at 25 ∘^\circ∘ C is x ×\times× 10 −-− 1. The value of x is ‾\underline{\hspace{2cm}}​. (Integer answer) 3HC≡CH(g)⇌C6H6(l)3HC \equiv C{H_{(g)}} \rightleftharpoons {C_6}{H_{6(l)}}3HC≡CH(g)​⇌C6​H6(l)​[Given : ΔfGo(HC≡CH)=−2.04×105{\Delta _f}{G^o}(HC \equiv CH) = - 2.04 \times {10^5}Δf​Go(HC≡CH)=−2.04×105 J mol −-− 1 ; ΔfGo(C6H6)=−1.24×105{\Delta _f}{G^o}({C_6}{H_6}) = - 1.24 \times {10^5}Δf​Go(C6​H6​)=−1.24×105 J mol −-− 1 ; R = 8.314 J K-1 mol −-− 1]
Numerical answer
View written solutionFree

Correct answer: 855

  1. Write the reaction

3 HC≡CH(g)⇌C6H6(l)3\,HC\equiv CH_{(g)} \rightleftharpoons C_6H_6{}_{(l)}3HC≡CH(g)​⇌C6​H6​(l)​

We use

ΔGrxn∘=∑νΔfG∘(products)−∑νΔfG∘(reactants)\Delta G^\circ_{\text{rxn}} = \sum \nu \Delta_f G^\circ(\text{products}) - \sum \nu \Delta_f G^\circ(\text{reactants})ΔGrxn∘​=∑νΔf​G∘(products)−∑νΔf​G∘(reactants)

  1. Calculate ΔGrxn∘\Delta G^\circ_{\text{rxn}}ΔGrxn∘​

Given:

ΔfG∘(HC≡CH)=−2.04×105  J mol−1\Delta_f G^\circ(HC\equiv CH) = -2.04\times 10^5\; \text{J mol}^{-1}Δf​G∘(HC≡CH)=−2.04×105J mol−1 ΔfG∘(C6H6)=−1.24×105  J mol−1\Delta_f G^\circ(C_6H_6) = -1.24\times 10^5\; \text{J mol}^{-1}Δf​G∘(C6​H6​)=−1.24×105J mol−1

So,

ΔGrxn∘=(−1.24×105)−3(−2.04×105)\Delta G^\circ_{\text{rxn}} = \left(-1.24\times 10^5\right) - 3\left(-2.04\times 10^5\right)ΔGrxn∘​=(−1.24×105)−3(−2.04×105)

=−1.24×105+6.12×105= -1.24\times 10^5 + 6.12\times 10^5=−1.24×105+6.12×105

=4.88×105  J mol−1= 4.88\times 10^5\; \text{J mol}^{-1}=4.88×105J mol−1

  1. Use the relation between ΔG∘\Delta G^\circΔG∘ and KKK

ΔG∘=−RTln⁡K\Delta G^\circ = -RT\ln KΔG∘=−RTlnK

Hence,

ln⁡K=−ΔG∘RT\ln K = -\frac{\Delta G^\circ}{RT}lnK=−RTΔG∘​

At 25∘C=298 K25^\circ C = 298\,K25∘C=298K,

ln⁡K=−4.88×1058.314×298\ln K = -\frac{4.88\times 10^5}{8.314\times 298}lnK=−8.314×2984.88×105​

First compute denominator:

8.314×298=2477.5728.314\times 298 = 2477.5728.314×298=2477.572

Thus,

ln⁡K≈−4.88×1052477.572≈−196.97\ln K \approx -\frac{4.88\times 10^5}{2477.572} \approx -196.97lnK≈−2477.5724.88×105​≈−196.97

  1. Convert to common logarithm

log⁡K=ln⁡K2.303\log K = \frac{\ln K}{2.303}logK=2.303lnK​

So,

log⁡K≈−196.972.303≈−85.53\log K \approx \frac{-196.97}{2.303} \approx -85.53logK≈2.303−196.97​≈−85.53

Therefore, the magnitude of log⁡K\log KlogK is

∣log⁡K∣≈85.53|\log K| \approx 85.53∣logK∣≈85.53

  1. Match with the form given

The question says magnitude of log⁡K\log KlogK is x×10−1x\times 10^{-1}x×10−1.

So,

x×10−1=85.53x\times 10^{-1} = 85.53x×10−1=85.53

x=855.3x = 855.3x=855.3

Since integer answer is required,

x=855x = 855x=855

  1. Comparison with stored answer

Stored correct answer = 855855855

This matches our derived answer.

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