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Thermodynamics question

2021 · 26 Feb · Shift 1 · Q17
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Thermodynamics question

2021 · 26 Feb · Shift 1 · Q17

JEE MainChemistryThermodynamicsNumerical+4 / −1
An exothermic reaction X →\to→ Y has an activation energy 30 kJ mol −-− 1. If energy change Δ\DeltaΔ E during the reaction is −-− 20 kJ, then the activation energy for the reverse reaction in kJ is ‾\underline{\hspace{2cm}}​. (Integer answer)
Numerical answer
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Correct answer: 50

  1. For the reaction X→YX \rightarrow YX→Y the forward activation energy is given as Ea,forward=30 kJ mol−1E_{a,\text{forward}} = 30\ \text{kJ mol}^{-1}Ea,forward​=30 kJ mol−1

  2. The energy change of the reaction is ΔE=EY−EX=−20 kJ mol−1\Delta E = E_Y - E_X = -20\ \text{kJ mol}^{-1}ΔE=EY​−EX​=−20 kJ mol−1 Since ΔE\Delta EΔE is negative, the reaction is exothermic, so product YYY lies 20 kJ mol−120\ \text{kJ mol}^{-1}20 kJ mol−1 below reactant XXX.

  3. Let the activated complex have energy E‡E^\ddaggerE‡. Then, Ea,forward=E‡−EX=30E_{a,\text{forward}} = E^\ddagger - E_X = 30Ea,forward​=E‡−EX​=30

  4. For the reverse reaction Y→XY \rightarrow XY→X, Ea,reverse=E‡−EYE_{a,\text{reverse}} = E^\ddagger - E_YEa,reverse​=E‡−EY​

  5. Using EY=EX+ΔE=EX−20E_Y = E_X + \Delta E = E_X - 20EY​=EX​+ΔE=EX​−20 we get Ea,reverse=E‡−(EX−20)E_{a,\text{reverse}} = E^\ddagger - (E_X - 20)Ea,reverse​=E‡−(EX​−20) =(E‡−EX)+20= (E^\ddagger - E_X) + 20=(E‡−EX​)+20 =30+20=50 kJ mol−1= 30 + 20 = 50\ \text{kJ mol}^{-1}=30+20=50 kJ mol−1

  6. Therefore, the activation energy for the reverse reaction is 50\boxed{50}50​

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