- A(A), (C) and (E) only
- B(B) and (C) only
- C(A), (B), (C) and (D) only
- D(A) and (E) only
View written solutionFree
Correct answer: C
- We need to identify processes in which entropy decreases.
Entropy, , generally decreases when:
- disorder decreases,
- gas moles decrease,
- particles become more ordered,
- molecules get fixed on surfaces.
Now evaluate each process.
- Option (A): Freezing of water to ice at C
Liquid water becomes solid ice, which is more ordered.
Therefore,
So, (A) is a process with decrease in entropy.
- Option (B): Freezing of water to ice at C
Again,
Freezing always converts a less ordered liquid into a more ordered solid, so system entropy decreases.
Hence,
So, (B) also shows decrease in entropy.
- Option (C):
Reactant gas moles moles of gas. Product gas moles moles of gas.
Decrease in number of gaseous molecules means less randomness.
Thus,
So, (C) is correct.
- Option (D): Adsorption of on lead surface
In adsorption, gas molecules lose freedom of motion and become attached to a surface. This increases order and decreases randomness.
Therefore,
So, (D) is also a process with decrease in entropy.
- Option (E): Dissolution of in water
Dissolution usually increases disorder because the ionic crystal breaks into solvated ions. Hence entropy generally increases.
Therefore,
So, (E) does not correspond to decrease in entropy.
- Collecting correct statements
Processes with entropy decrease are:
- (A)
- (B)
- (C)
- (D)
Thus the correct option is:
which corresponds to (A), (B), (C) and (D) only.
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