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Structure of Atom question

2023 · 15 Apr · Shift 1 · Q8
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  5. /2023 · 15 Apr · Shift 1 · Q8

Structure of Atom question

2023 · 15 Apr · Shift 1 · Q8

JEE MainChemistryStructure of AtomMCQ+4 / −1
Given below are two statements: Statement I : According to Bohr's model of hydrogen atom, the angular momentum of an electron in a given stationary state is quantised. Statement II : The concept of electron in Bohr's orbit, violates the Heisenberg uncertainty principle. In the light of the above statements, choose the most appropriate answer from the options given below:
  1. A
    Both Statement I and Statement II are incorrect
  2. B
    Statement I is correct but Statement II is incorrect
  3. C
    Both Statement I and Statement II are correct
  4. D
    Statement I is incorrect but Statement II is correct
View written solutionFree

Correct answer: C

  1. Analyze Statement I

    According to Bohr’s model, the electron can move only in certain allowed circular orbits, called stationary states.

    Bohr’s quantisation condition is: mvr=nh2π=nℏmvr = \frac{nh}{2\pi} = n\hbarmvr=2πnh​=nℏ where n=1,2,3,…n = 1,2,3,\dotsn=1,2,3,…

    Since angular momentum is: L=mvrL = mvrL=mvr it follows that: L=nℏL = n\hbarL=nℏ

    Therefore, the angular momentum of the electron is quantised in a stationary state.

    So, Statement I is correct.

  2. Analyze Statement II

    In Bohr’s model, the electron is assumed to revolve in a definite circular orbit with fixed radius and fixed momentum.

    That means both the position and momentum of the electron are being specified simultaneously with precision.

    But Heisenberg’s uncertainty principle states: Δx Δp≥ℏ2\Delta x\, \Delta p \ge \frac{\hbar}{2}ΔxΔp≥2ℏ​

    Hence, assigning a definite orbit to the electron is inconsistent with the uncertainty principle.

    So, Statement II is also correct.

  3. Evaluate the options

    • A: Both incorrect — false
    • B: Statement I correct, Statement II incorrect — false
    • C: Both correct — true
    • D: Statement I incorrect, Statement II correct — false
  4. Final Answer

    The correct option is: C\boxed{\text{C}}C​

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