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Structure of Atom question

2023 · 29 Jan · Shift 2 · Q22
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Structure of Atom question

2023 · 29 Jan · Shift 2 · Q22

JEE MainChemistryStructure of AtomNumerical+4 / −1
Assume that the radius of the first Bohr orbit of hydrogen atom is 0.6 Ao\mathrm{\mathop A\limits^o }Ao​. The radius of the third Bohr orbit of He +^++ is ‾\underline{\hspace{2cm}}​ picometer. (Nearest Integer)
Numerical answer
View written solutionFree

Correct answer: 270

  1. Bohr radius formula

    For a hydrogen-like species, the radius of the nnnth Bohr orbit is rn=a0n2Zr_n = a_0\frac{n^2}{Z}rn​=a0​Zn2​ where:

    • a0a_0a0​ = radius of first Bohr orbit of hydrogen
    • nnn = orbit number
    • ZZZ = atomic number
  2. Given data

    • First Bohr orbit radius of hydrogen:
      a0=0.6 A˚a_0 = 0.6\,\text{\AA}a0​=0.6A˚
    • For He+\text{He}^+He+, atomic number: Z=2Z=2Z=2
    • Required orbit: third orbit, so n=3n=3n=3
  3. Calculate radius of third orbit of He+\text{He}^+He+

    r3=a0322=0.6×92 A˚r_3 = a_0\frac{3^2}{2} = 0.6\times \frac{9}{2}\,\text{\AA}r3​=a0​232​=0.6×29​A˚

    r3=0.6×4.5=2.7 A˚r_3 = 0.6\times 4.5 = 2.7\,\text{\AA}r3​=0.6×4.5=2.7A˚

  4. Convert \AA to picometer

    1 A˚=100 pm1\,\text{\AA} = 100\,\text{pm}1A˚=100pm

    Therefore, 2.7 A˚=2.7×100=270 pm2.7\,\text{\AA} = 2.7\times 100 = 270\,\text{pm}2.7A˚=2.7×100=270pm

  5. Final answer

    The radius of the third Bohr orbit of He+\text{He}^+He+ is 270 pm\boxed{270\,\text{pm}}270pm​

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