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Structure of Atom question

2023 · 24 Jan · Shift 2 · Q1
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Structure of Atom question

2023 · 24 Jan · Shift 2 · Q1

JEE MainChemistryStructure of AtomMCQ+4 / −1
The number of s-electrons present in an ion with 55 protons in its unipositive state is
  1. A
    10
  2. B
    9
  3. C
    12
  4. D
    8
View written solutionFree

Correct answer: A

  1. Identify the element
    An ion with 55 protons has atomic number Z=55Z=55Z=55, which is cesium (Cs).

  2. Write the electronic configuration of neutral cesium
    Cesium has 55 electrons in the neutral state: Cs:1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s1\mathrm{Cs}: 1s^2\,2s^2\,2p^6\,3s^2\,3p^6\,4s^2\,3d^{10}\,4p^6\,5s^2\,4d^{10}\,5p^6\,6s^1Cs:1s22s22p63s23p64s23d104p65s24d105p66s1 Or briefly, Cs=[Xe]6s1\mathrm{Cs} = [Xe]6s^1Cs=[Xe]6s1

  3. Form the unipositive ion
    Unipositive state means Cs+\mathrm{Cs}^+Cs+, so one electron is removed from the outermost orbital 6s6s6s: Cs+=[Xe]\mathrm{Cs}^+ = [Xe]Cs+=[Xe] Thus the configuration becomes: 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p61s^2\,2s^2\,2p^6\,3s^2\,3p^6\,4s^2\,3d^{10}\,4p^6\,5s^2\,4d^{10}\,5p^61s22s22p63s23p64s23d104p65s24d105p6

  4. Count the total number of sss-electrons
    The occupied sss-subshells are:

  • 1s21s^21s2 →2\to 2→2
  • 2s22s^22s2 →2\to 2→2
  • 3s23s^23s2 →2\to 2→2
  • 4s24s^24s2 →2\to 2→2
  • 5s25s^25s2 →2\to 2→2
  • 6s06s^06s0 →0\to 0→0 (removed in Cs+\mathrm{Cs}^+Cs+)

Total number of sss-electrons: 2+2+2+2+2=102+2+2+2+2=102+2+2+2+2=10

  1. Evaluate options
  • A: 101010 ✅
  • B: 999 ❌
  • C: 121212 ❌
  • D: 888 ❌

Therefore, the correct answer is A.

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