Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Structure of Atom question

2023 · 29 Jan · Shift 1 · Q7
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Structure of Atom
  5. /2023 · 29 Jan · Shift 1 · Q7

Structure of Atom question

2023 · 29 Jan · Shift 1 · Q7

JEE MainChemistryStructure of AtomMCQ+4 / −1
The shortest wavelength of hydrogen atom in Lyman series is λ\lambdaλ. The longest wavelength is Balmer series of He +^++ is
  1. A
    36λ5\frac{36\lambda}{5}536λ​
  2. B
    59λ\frac{5}{9\lambda}9λ5​
  3. C
    9λ5\frac{9\lambda}{5}59λ​
  4. D
    5λ9\frac{5\lambda}{9}95λ​
View written solutionFree

Correct answer: C

  1. Given:

    • Shortest wavelength of hydrogen atom in Lyman series is λ\lambdaλ.
    • We need the longest wavelength in Balmer series of He+^++.
  2. Shortest wavelength in Lyman series of H

    For hydrogen-like species, 1λ=RZ2(1n12−1n22)\frac{1}{\lambda}=RZ^2\left(\frac{1}{n_1^2}-\frac{1}{n_2^2}\right)λ1​=RZ2(n12​1​−n22​1​)

    In the Lyman series, n1=1n_1=1n1​=1. The shortest wavelength corresponds to n2=∞n_2=\inftyn2​=∞.

    So for hydrogen (Z=1Z=1Z=1): 1λ=R(1−0)=R\frac{1}{\lambda}=R\left(1-0\right)=Rλ1​=R(1−0)=R Hence, λ=1R\lambda=\frac{1}{R}λ=R1​

  3. Longest wavelength in Balmer series of He+^++

    For Balmer series, n1=2n_1=2n1​=2. The longest wavelength corresponds to the smallest transition in that series, i.e. n2=3→n1=2n_2=3 \to n_1=2n2​=3→n1​=2.

    For He+^++, Z=2Z=2Z=2.

    Therefore, 1λ′=R(2)2(122−132)\frac{1}{\lambda'}=R(2)^2\left(\frac{1}{2^2}-\frac{1}{3^2}\right)λ′1​=R(2)2(221​−321​) 1λ′=4R(14−19)\frac{1}{\lambda'}=4R\left(\frac{1}{4}-\frac{1}{9}\right)λ′1​=4R(41​−91​) 1λ′=4R(536)=5R9\frac{1}{\lambda'}=4R\left(\frac{5}{36}\right)=\frac{5R}{9}λ′1​=4R(365​)=95R​

    Thus, λ′=95R\lambda'=\frac{9}{5R}λ′=5R9​

  4. Use λ=1R\lambda=\frac{1}{R}λ=R1​

    Since λ=1R\lambda=\frac{1}{R}λ=R1​, λ′=95λ\lambda'=\frac{9}{5}\lambdaλ′=59​λ

  5. Match with options

    λ′=9λ5\boxed{\lambda'=\frac{9\lambda}{5}}λ′=59λ​​

    So the correct option is C.

PreviousNext

More from Structure of Atom

  • Assume that the radius of the first Bohr orbit of hydrogen atom is 0.6 Ao​. The radius of the third Bohr orbit of He + is ​ picometer. (Nearest Integer)2023 · Numerical
  • The energy of one mole of photons of radiation of frequency 2×1012 Hz in J mol−1 is ​. (Nearest integer) [Given : h=6.626×10−34 Js NA​=6.022×1023 mol−1…2023 · Numerical
  • Maximum number of electrons that can be accommodated in shell with n=4 are:2023 · MCQ
  • The wave function (Ψ) of 2 s is given by Ψ2 s​=22π​1​(a0​1​)1/2(2−a0​r​)e−r/2a0​ At r=r0​, radial node is formed. Thus, r0​ in…2023 · MCQ
  • Which transition in the hydrogen spectrum would have the same wavelength as the Balmer type transition from n=4 to n=2 of He+ spectrum2023 · MCQ
  • Arrange the following orbitals in decreasing order of energy. A. n=3,l=0, m=0 B. n=4,l=0, m=0 C. n=3,l=1, m=0 D. n=3,l=2, m=1…2023 · MCQ
  • Consider the following pairs of electrons (A) (a) n = 3, l= 1, m1 = 1, ms = +21​(b) n = 3, 1 = 2, m1 = 1, ms = +21​(B) (a) n = 3, l= 2, m1 =− 2, ms = −21​(b) n = 3, l= 2, m1 =− 1, ms = $-{1 \over…2022 · MCQ
  • The energy of one mole of photons of radiation of wavelength 300 nm is (Given : h = 6.63 × 10 − 34 J s, NA = 6.02 × 1023 mol − 1, c = 3 × 108 m s − 1)2022 · MCQ