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Structure of Atom question

2003 · Shift 0 · Q56
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Structure of Atom question

2003 · Shift 0 · Q56

JEE MainChemistryStructure of AtomMCQ+4 / −1
The orbital angular momentum for an electron revolving in an orbit is given by l(l+1)h2π\sqrt {l(l + 1)} {h \over {2\pi }}l(l+1)​2πh​. This momentum for an s-electron will be given by
  1. A
    zero
  2. B
    h2π{h \over {2\pi }}2πh​
  3. C
    2h2π\sqrt 2 {h \over {2\pi }}2​2πh​
  4. D
    +12h2π+ {1 \over 2}{h \over {2\pi }}+21​2πh​
View written solutionFree

Correct answer: A

  1. The magnitude of orbital angular momentum of an electron is given by

L=l(l+1) h2πL = \sqrt{l(l+1)}\,\frac{h}{2\pi}L=l(l+1)​2πh​

where lll is the azimuthal quantum number.

  1. For an sss-electron, the orbital is an sss-orbital, so

l=0l = 0l=0

  1. Substitute l=0l=0l=0 into the formula:

L=0(0+1) h2πL = \sqrt{0(0+1)}\,\frac{h}{2\pi}L=0(0+1)​2πh​

L=0 h2π=0L = \sqrt{0}\,\frac{h}{2\pi} = 0L=0​2πh​=0

  1. Therefore, the orbital angular momentum for an sss-electron is

000

  1. Checking options:
  • A: zero — correct
  • B: h2π\dfrac{h}{2\pi}2πh​ — incorrect
  • C: 2h2π\sqrt{2}\dfrac{h}{2\pi}2​2πh​ — incorrect
  • D: +12h2π+\dfrac{1}{2}\dfrac{h}{2\pi}+21​2πh​ — incorrect

Hence, the correct answer is A.

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