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Structure of Atom question

2002 · Shift 0 · Q56
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Structure of Atom question

2002 · Shift 0 · Q56

JEE MainChemistryStructure of AtomMCQ+4 / −1
In a hydrogen atom, if energy of an electron in ground state is -13.6 eV, then that in the 2nd excited state is
  1. A
    -1.51 eV
  2. B
    -3.4 eV
  3. C
    -6.04 eV
  4. D
    -13.6 eV
View written solutionFree

Correct answer: A

  1. Use the energy formula for hydrogen atom

    The energy of the electron in the nnnth orbit of hydrogen is En=−13.6n2 eVE_n = \frac{-13.6}{n^2}\,\text{eV}En​=n2−13.6​eV

  2. Identify the 2nd excited state

    • Ground state →n=1\to n=1→n=1
    • 1st excited state →n=2\to n=2→n=2
    • 2nd excited state →n=3\to n=3→n=3

    So we need the energy at n=3n=3n=3.

  3. Calculate the energy

    E3=−13.632=−13.69E_3 = \frac{-13.6}{3^2} = \frac{-13.6}{9}E3​=32−13.6​=9−13.6​

    E3≈−1.51 eVE_3 \approx -1.51\,\text{eV}E3​≈−1.51eV

  4. Compare with options

    • A: −1.51 eV-1.51\,\text{eV}−1.51eV ✅
    • B: −3.4 eV-3.4\,\text{eV}−3.4eV
    • C: −6.04 eV-6.04\,\text{eV}−6.04eV
    • D: −13.6 eV-13.6\,\text{eV}−13.6eV

Therefore, the correct answer is A.

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