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Some Basic Concepts of Chemistry question

2024 · 29 Jan · Shift 2 · Q30
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Some Basic Concepts of Chemistry question

2024 · 29 Jan · Shift 2 · Q30

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
Molality of 0.8 M H 2_22​ SO 4_44​ solution (density 1.06 g cm −3^{-3}−3) is ‾×10−3\underline{\hspace{2cm}}\times10^{-3}​×10−3 m.
Numerical answer
View written solutionFree

Correct answer: 815

  1. Given data

    • Molarity of solution: 0.8 M0.8\,M0.8M
    • Density of solution: 1.06 g cm−3=1.06 g mL−11.06\,\text{g cm}^{-3} = 1.06\,\text{g mL}^{-1}1.06g cm−3=1.06g mL−1
    • Solute: H2SO4\mathrm{H_2SO_4}H2​SO4​
  2. Take 1 litre of solution Since molarity is given, in 1 L1\,\text{L}1L solution: moles of H2SO4=0.8\text{moles of } \mathrm{H_2SO_4} = 0.8moles of H2​SO4​=0.8

  3. Mass of 1 litre solution mass of solution=1000 mL×1.06 gmL=1060 g\text{mass of solution} = 1000\,\text{mL} \times 1.06\,\frac{\text{g}}{\text{mL}} = 1060\,\text{g}mass of solution=1000mL×1.06mLg​=1060g

  4. Mass of solute Molar mass of H2SO4\mathrm{H_2SO_4}H2​SO4​: 2(1)+32+4(16)=98 g mol−12(1) + 32 + 4(16) = 98\,\text{g mol}^{-1}2(1)+32+4(16)=98g mol−1 So, mass of 0.80.80.8 mol acid: 0.8×98=78.4 g0.8 \times 98 = 78.4\,\text{g}0.8×98=78.4g

  5. Mass of solvent mass of solvent=1060−78.4=981.6 g=0.9816 kg\text{mass of solvent} = 1060 - 78.4 = 981.6\,\text{g} = 0.9816\,\text{kg}mass of solvent=1060−78.4=981.6g=0.9816kg

  6. Calculate molality m=moles of solutekg of solvent=0.80.9816m = \frac{\text{moles of solute}}{\text{kg of solvent}} = \frac{0.8}{0.9816}m=kg of solventmoles of solute​=0.98160.8​ m≈0.81499 mol kg−1m \approx 0.81499\,\text{mol kg}^{-1}m≈0.81499mol kg−1 m≈0.815 mm \approx 0.815\,mm≈0.815m

  7. Match with asked format The question writes molality as: ‾×10−3 m\underline{\hspace{2cm}}\times 10^{-3}\,m​×10−3m But the calculated molality is clearly: 0.815 m=815×10−3 m0.815\,m = 815 \times 10^{-3}\,m0.815m=815×10−3m

Therefore, the required integer is: 815\boxed{815}815​

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