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Some Basic Concepts of Chemistry question

2024 · 27 Jan · Shift 2 · Q27
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Some Basic Concepts of Chemistry question

2024 · 27 Jan · Shift 2 · Q27

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
9.3 g9.3 \mathrm{~g}9.3 g of aniline is subjected to reaction with excess of acetic anhydride to prepare acetanilide. The mass of acetanilide produced if the reaction is 100%100 \%100% completed is ‾\underline{\hspace{2cm}}​×10−1 g\times 10^{-1} \mathrm{~g}×10−1 g. (Given molar mass in g mol−1\mathrm{g} \mathrm{~mol}^{-1}g mol−1 N:14,O:16,C:12,H:1 ) \begin{aligned} & \mathrm{N}: 14, \mathrm{O}: 16, \\ & \mathrm{C}: 12, \mathrm{H}: 1 \text { ) } \end{aligned}​N:14,O:16,C:12,H:1 ) ​
Numerical answer
View written solutionFree

Correct answer: 135

  1. Write the reaction

Aniline reacts with acetic anhydride to give acetanilide:

C6H5NH2+(CH3CO)2O→C6H5NHCOCH3+CH3COOH\mathrm{C_6H_5NH_2 + (CH_3CO)_2O \rightarrow C_6H_5NHCOCH_3 + CH_3COOH}C6​H5​NH2​+(CH3​CO)2​O→C6​H5​NHCOCH3​+CH3​COOH

So, the mole ratio of aniline to acetanilide is:

1:11:11:1

  1. Find molar mass of aniline

Aniline has formula C6H5NH2\mathrm{C_6H_5NH_2}C6​H5​NH2​, i.e. C6H7N\mathrm{C_6H_7N}C6​H7​N.

M(aniline)=6(12)+7(1)+14=72+7+14=93 g mol−1M(\text{aniline}) = 6(12) + 7(1) + 14 = 72 + 7 + 14 = 93\ \mathrm{g\,mol^{-1}}M(aniline)=6(12)+7(1)+14=72+7+14=93 gmol−1

  1. Calculate moles of aniline

Given mass of aniline =9.3 g= 9.3\ \mathrm{g}=9.3 g

n(aniline)=9.393=0.1 moln(\text{aniline}) = \frac{9.3}{93} = 0.1\ \mathrm{mol}n(aniline)=939.3​=0.1 mol

  1. Find molar mass of acetanilide

Acetanilide has formula C6H5NHCOCH3\mathrm{C_6H_5NHCOCH_3}C6​H5​NHCOCH3​, i.e. C8H9NO\mathrm{C_8H_9NO}C8​H9​NO.

M(acetanilide)=8(12)+9(1)+14+16=96+9+14+16=135 g mol−1M(\text{acetanilide}) = 8(12) + 9(1) + 14 + 16 = 96 + 9 + 14 + 16 = 135\ \mathrm{g\,mol^{-1}}M(acetanilide)=8(12)+9(1)+14+16=96+9+14+16=135 gmol−1

  1. Calculate mass of acetanilide formed

Since mole ratio is 1:11:11:1,

n(acetanilide)=0.1 moln(\text{acetanilide}) = 0.1\ \mathrm{mol}n(acetanilide)=0.1 mol

Therefore,

m(acetanilide)=0.1×135=13.5 gm(\text{acetanilide}) = 0.1 \times 135 = 13.5\ \mathrm{g}m(acetanilide)=0.1×135=13.5 g

  1. Match with the form asked in the question

The mass is written as:

‾×10−1 g\underline{\hspace{2cm}} \times 10^{-1}\ \mathrm{g}​×10−1 g

Now,

13.5 g=135×10−1 g13.5\ \mathrm{g} = 135 \times 10^{-1}\ \mathrm{g}13.5 g=135×10−1 g

So the required integer is:

135\boxed{135}135​

  1. Comparison with stored answer

Stored correct answer = 135135135

Our derived answer also = 135135135, so they agree.

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