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Some Basic Concepts of Chemistry question

2024 · 9 Apr · Shift 1 · Q30
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Some Basic Concepts of Chemistry question

2024 · 9 Apr · Shift 1 · Q30

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
Molarity (M)(\mathrm{M})(M) of an aqueous solution containing x gx \mathrm{~g}x g of anhyd. CuSO4\mathrm{CuSO}_4CuSO4​ in 500 mL500 \mathrm{~mL}500 mL solution at 32∘C32^{\circ} \mathrm{C}32∘C is 2×10−1M2 \times 10^{-1} \mathrm{M}2×10−1M. Its molality will be ‾×10−3 m\underline{\hspace{2cm}}\times 10^{-3} \mathrm{~m}​×10−3 m. (nearest integer). [Given density of the solution =1.25 g/mL=1.25 \mathrm{~g} / \mathrm{mL}=1.25 g/mL]
Numerical answer
View written solutionFree

Correct answer: 164

  1. Given data

    • Molarity of solution: M=2×10−1=0.2 mol L−1M = 2 \times 10^{-1} = 0.2\,\text{mol L}^{-1}M=2×10−1=0.2mol L−1
    • Volume of solution: 500 mL=0.5 L500\,\text{mL} = 0.5\,\text{L}500mL=0.5L
    • Density of solution: 1.25 g mL−11.25\,\text{g mL}^{-1}1.25g mL−1
    • Solute: anhydrous CuSO4\text{CuSO}_4CuSO4​
  2. Find moles of CuSO4\text{CuSO}_4CuSO4​ in 500 mL solution

    Using moles=M×V\text{moles} = M \times Vmoles=M×V n=0.2×0.5=0.1 moln = 0.2 \times 0.5 = 0.1\,\text{mol}n=0.2×0.5=0.1mol

  3. Find mass of solute

    Molar mass of CuSO4\text{CuSO}_4CuSO4​: Mr=63.5+32+4(16)=159.5 g mol−1M_r = 63.5 + 32 + 4(16) = 159.5\,\text{g mol}^{-1}Mr​=63.5+32+4(16)=159.5g mol−1

    So mass of solute is msolute=0.1×159.5=15.95 gm_{\text{solute}} = 0.1 \times 159.5 = 15.95\,\text{g}msolute​=0.1×159.5=15.95g

  4. Find mass of solution

    Using density, mass of solution=1.25×500=625 g\text{mass of solution} = 1.25 \times 500 = 625\,\text{g}mass of solution=1.25×500=625g

  5. Find mass of solvent (water)

    msolvent=625−15.95=609.05 g=0.60905 kgm_{\text{solvent}} = 625 - 15.95 = 609.05\,\text{g} = 0.60905\,\text{kg}msolvent​=625−15.95=609.05g=0.60905kg

  6. Calculate molality

    molality=moles of solutekg of solvent\text{molality} = \frac{\text{moles of solute}}{\text{kg of solvent}}molality=kg of solventmoles of solute​ m=0.10.60905=0.16419 mol kg−1m = \frac{0.1}{0.60905} = 0.16419\,\text{mol kg}^{-1}m=0.609050.1​=0.16419mol kg−1

  7. Match with the asked form

    The question asks: ‾×10−3 m\underline{\hspace{1cm}} \times 10^{-3}\,m​×10−3m

    Since 0.16419=164.19×10−30.16419 = 164.19 \times 10^{-3}0.16419=164.19×10−3

    Nearest integer =164= 164=164.

  8. Final answer

    164\boxed{164}164​

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