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Some Basic Concepts of Chemistry question

2024 · 4 Apr · Shift 2 · Q24
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Some Basic Concepts of Chemistry question

2024 · 4 Apr · Shift 2 · Q24

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
From 6.55 g6.55 \mathrm{~g}6.55 g of aniline, the maximum amount of acetanilide that can be prepared will be ‾\underline{\hspace{2cm}}​×10−1 g\times 10^{-1} \mathrm{~g}×10−1 g.
Numerical answer
View written solutionFree

Correct answer: 95

  1. Write the reaction conceptually

Aniline reacts with an acetylating agent to form acetanilide in a 1 : 1 molar ratio.

Aniline→Acetanilide\text{Aniline} \rightarrow \text{Acetanilide}Aniline→Acetanilide

So, moles of acetanilide formed = moles of aniline taken.


  1. Calculate molar mass of aniline

Aniline is C6H5NH2=C6H7N\mathrm{C_6H_5NH_2} = \mathrm{C_6H_7N}C6​H5​NH2​=C6​H7​N

M(aniline)=6×12+7×1+14=72+7+14=93 g mol−1M(\text{aniline}) = 6\times 12 + 7\times 1 + 14 = 72 + 7 + 14 = 93\,\mathrm{g\,mol^{-1}}M(aniline)=6×12+7×1+14=72+7+14=93gmol−1


  1. Find moles of aniline

Given mass of aniline = 6.55 g6.55\,\mathrm{g}6.55g

n(aniline)=6.5593n(\text{aniline}) = \frac{6.55}{93}n(aniline)=936.55​

n(aniline)≈0.07043 moln(\text{aniline}) \approx 0.07043\,\mathrm{mol}n(aniline)≈0.07043mol


  1. Calculate molar mass of acetanilide

Acetanilide is C6H5NHCOCH3=C8H9NO\mathrm{C_6H_5NHCOCH_3} = \mathrm{C_8H_9NO}C6​H5​NHCOCH3​=C8​H9​NO

M(acetanilide)=8×12+9×1+14+16=96+9+14+16=135 g mol−1M(\text{acetanilide}) = 8\times 12 + 9\times 1 + 14 + 16 = 96 + 9 + 14 + 16 = 135\,\mathrm{g\,mol^{-1}}M(acetanilide)=8×12+9×1+14+16=96+9+14+16=135gmol−1


  1. Find mass of acetanilide formed

Since molar ratio is 1:11:11:1,

n(acetanilide)=0.07043 moln(\text{acetanilide}) = 0.07043\,\mathrm{mol}n(acetanilide)=0.07043mol

Hence,

m(acetanilide)=n×M=0.07043×135m(\text{acetanilide}) = n \times M = 0.07043 \times 135m(acetanilide)=n×M=0.07043×135

m(acetanilide)≈9.51 gm(\text{acetanilide}) \approx 9.51\,\mathrm{g}m(acetanilide)≈9.51g


  1. Match with the required format

The question asks:

‾×10−1 g\underline{\hspace{2cm}} \times 10^{-1}\,\mathrm{g}​×10−1g

Now,

9.51 g=95.1×10−1 g9.51\,\mathrm{g} = 95.1 \times 10^{-1}\,\mathrm{g}9.51g=95.1×10−1g

So the required integer is

95\boxed{95}95​


  1. Comparison with stored correct answer

Stored correct answer = 959595

Our derived answer = 959595

So they agree.

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