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Some Basic Concepts of Chemistry question

2021 · 24 Feb · Shift 2 · Q17
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Some Basic Concepts of Chemistry question

2021 · 24 Feb · Shift 2 · Q17

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
1.86 g of aniline completely reacts to form acetanilide. 10% of the product is lost during purification. Amount of acetanilide obtained after purification (in g) is ‾×\underline{\hspace{2cm}}\times​× 10 −-− 2.
Numerical answer
View written solutionFree

Correct answer: 243

  1. Write the reaction idea

Aniline reacts to give acetanilide in a 1:11:11:1 mole ratio.

So, n(aniline)=n(acetanilide)n(\text{aniline}) = n(\text{acetanilide})n(aniline)=n(acetanilide)

  1. Molar masses
  • Aniline: C6H5NH2=C6H7N\mathrm{C_6H_5NH_2} = \mathrm{C_6H_7N}C6​H5​NH2​=C6​H7​N M=6×12+7×1+14=72+7+14=93 g mol−1M = 6\times 12 + 7\times 1 + 14 = 72 + 7 + 14 = 93\,\text{g mol}^{-1}M=6×12+7×1+14=72+7+14=93g mol−1

  • Acetanilide: C8H9NO\mathrm{C_8H_9NO}C8​H9​NO M=8×12+9×1+14+16=96+9+14+16=135 g mol−1M = 8\times 12 + 9\times 1 + 14 + 16 = 96 + 9 + 14 + 16 = 135\,\text{g mol}^{-1}M=8×12+9×1+14+16=96+9+14+16=135g mol−1

  1. Moles of aniline taken

Given mass of aniline =1.86 = 1.86\,=1.86g

n(aniline)=1.8693=0.02 moln(\text{aniline}) = \frac{1.86}{93} = 0.02\,\text{mol}n(aniline)=931.86​=0.02mol

Therefore, n(acetanilide formed)=0.02 moln(\text{acetanilide formed}) = 0.02\,\text{mol}n(acetanilide formed)=0.02mol

  1. Theoretical mass of acetanilide

m=nM=0.02×135=2.70 gm = nM = 0.02 \times 135 = 2.70\,\text{g}m=nM=0.02×135=2.70g

  1. Loss during purification

10%10\%10% of product is lost, so 90%90\%90% is obtained.

mobtained=0.9×2.70=2.43 gm_{\text{obtained}} = 0.9 \times 2.70 = 2.43\,\text{g}mobtained​=0.9×2.70=2.43g

  1. Match with the required form

Given form: ‾×10−2\underline{\hspace{2cm}} \times 10^{-2}​×10−2

Now, 2.43=243×10−22.43 = 243 \times 10^{-2}2.43=243×10−2

So the required integer is: 243\boxed{243}243​

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