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Some Basic Concepts of Chemistry question

2021 · 26 Feb · Shift 2 · Q25
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Some Basic Concepts of Chemistry question

2021 · 26 Feb · Shift 2 · Q25

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
The NaNO3NaNO_3NaNO3​ weighed out to make 50 mL of an aqueous solution containing 70.0 mg Na+Na^+Na+ per mL is ‾\underline{\hspace{2cm}}​ g. (Rounded off to the nearest integer) [Given : Atomic weight in g mol −-− 1 - NaNaNa : 23; N : 14; O : 16]
Numerical answer
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Correct answer: 13

  1. Find total mass of Na+Na^+Na+ required

Given concentration of sodium ions is 70.0 mg mL−170.0\ \text{mg mL}^{-1}70.0 mg mL−1 and total volume is 50 mL50\ \text{mL}50 mL.

So total mass of Na+Na^+Na+ needed is:

70.0×50=3500 mg=3.5 g70.0\times 50 = 3500\ \text{mg} = 3.5\ \text{g}70.0×50=3500 mg=3.5 g

  1. Relate NaNO3NaNO_3NaNO3​ to Na+Na^+Na+

Each mole of NaNO3NaNO_3NaNO3​ gives one mole of Na+Na^+Na+.

Molar mass of NaNO3NaNO_3NaNO3​:

23+14+3×16=23+14+48=85 g mol−123 + 14 + 3\times 16 = 23+14+48 = 85\ \text{g mol}^{-1}23+14+3×16=23+14+48=85 g mol−1

Thus, 85 g85\ \text{g}85 g of NaNO3NaNO_3NaNO3​ contains 23 g23\ \text{g}23 g of Na+Na^+Na+.

  1. Use mass ratio

If 23 g23\ \text{g}23 g of Na+Na^+Na+ comes from 85 g85\ \text{g}85 g of NaNO3NaNO_3NaNO3​, then 3.5 g3.5\ \text{g}3.5 g of Na+Na^+Na+ will come from:

mass of NaNO3=3.5×8523\text{mass of } NaNO_3 = 3.5\times \frac{85}{23}mass of NaNO3​=3.5×2385​

=297.523≈12.93 g= \frac{297.5}{23} \approx 12.93\ \text{g}=23297.5​≈12.93 g

  1. Round to nearest integer

12.93≈1312.93 \approx 1312.93≈13

So, the required mass of NaNO3NaNO_3NaNO3​ is:

13 g\boxed{13\ \text{g}}13 g​

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