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Some Basic Concepts of Chemistry question

2021 · 24 Feb · Shift 2 · Q15
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Some Basic Concepts of Chemistry question

2021 · 24 Feb · Shift 2 · Q15

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
The formula of a gaseous hydrocarbon which requires 6 times of its own volume of O2O_2O2​ for complete oxidation and produces 4 times its own volume of CO2CO_2CO2​ is CxHy. The value of y is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 8

  1. Let the gaseous hydrocarbon be CxHy\mathrm{C_xH_y}Cx​Hy​.

  2. For complete combustion, the balanced reaction is:

CxHy+(x+y4)O2→xCO2+y2H2O\mathrm{C_xH_y + \left(x + \frac{y}{4}\right)O_2 \rightarrow xCO_2 + \frac{y}{2}H_2O}Cx​Hy​+(x+4y​)O2​→xCO2​+2y​H2​O
  1. Since all gases are compared at the same temperature and pressure, volumes are proportional to mole ratios.

  2. Given:

  • Hydrocarbon requires 666 times its own volume of O2O_2O2​
  • Hydrocarbon produces 444 times its own volume of CO2CO_2CO2​

So from the reaction stoichiometry:

x+y4=6x + \frac{y}{4} = 6x+4y​=6

and

x=4x = 4x=4
  1. Substitute x=4x=4x=4 into the first equation:
4+y4=64 + \frac{y}{4} = 64+4y​=6 y4=2\frac{y}{4} = 24y​=2 y=8y = 8y=8
  1. Therefore, the hydrocarbon is C4H8\mathrm{C_4H_8}C4​H8​, and the required value is:
8\boxed{8}8​

Comparison with stored correct answer:

  • Derived answer = 888
  • Stored correct answer = 888
  • They match.
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