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Some Basic Concepts of Chemistry question

2021 · 25 Feb · Shift 1 · Q10
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Some Basic Concepts of Chemistry question

2021 · 25 Feb · Shift 1 · Q10

JEE MainChemistrySome Basic Concepts of ChemistryMCQ+4 / −1
Complete combustion of 1.80 g of an oxygen containing compound (CxHyOzC_xH_yO_zCx​Hy​Oz​) gave 2.64 g of CO2CO_2CO2​ and 1.08 g of H2OH_2OH2​O. The percentage of oxygen in the organic compound is :
  1. A
    51.63
  2. B
    50.33
  3. C
    63.53
  4. D
    53.33
View written solutionFree

Correct answer: D

  1. Find mass of carbon in the compound

From combustion: 2.64 g CO22.64\,\text{g } CO_22.64g CO2​

In 444444 g of CO2CO_2CO2​, mass of carbon is 121212 g. So, mass of carbon in 2.642.642.64 g CO2CO_2CO2​ is mC=2.64×1244=0.72 gm_C = 2.64 \times \frac{12}{44} = 0.72\,\text{g}mC​=2.64×4412​=0.72g

  1. Find mass of hydrogen in the compound

From combustion: 1.08 g H2O1.08\,\text{g } H_2O1.08g H2​O

In 181818 g of H2OH_2OH2​O, mass of hydrogen is 222 g. So, mass of hydrogen in 1.081.081.08 g H2OH_2OH2​O is mH=1.08×218=0.12 gm_H = 1.08 \times \frac{2}{18} = 0.12\,\text{g}mH​=1.08×182​=0.12g

  1. Find mass of oxygen in the original compound

Total mass of compound burnt = 1.801.801.80 g

Hence, mO=1.80−(0.72+0.12)=1.80−0.84=0.96 gm_O = 1.80 - (0.72 + 0.12) = 1.80 - 0.84 = 0.96\,\text{g}mO​=1.80−(0.72+0.12)=1.80−0.84=0.96g

  1. Calculate percentage of oxygen

%O=0.961.80×100\%O = \frac{0.96}{1.80} \times 100%O=1.800.96​×100

%O=53.33%\%O = 53.33\%%O=53.33%

  1. Match with options

Thus the correct option is: D: 53.33\boxed{\text{D: }53.33}D: 53.33​

  1. Comparison with stored answer

Stored correct answer is D, which matches our derived answer.

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