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Solutions question

2025 · 4 Apr · Shift 2 · Q21
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Solutions question

2025 · 4 Apr · Shift 2 · Q21

JEE MainChemistrySolutionsNumerical+4 / −1
Sea water, which can be considered as a 6 molar (6M)(6 \mathrm{M})(6M) solution of NaCl , has a density of 2 g mL−12 \mathrm{~g} \mathrm{~mL}^{-1}2 g mL−1. The concentration of dissolved oxygen (O2)\left(\mathrm{O}_2\right)(O2​) in sea water is 5.8 ppm . Then the concentration of dissolved oxygen (O2)\left(\mathrm{O}_2\right)(O2​) in sea water, is x×10−4 mx \times 10^{-4} \mathrm{~m}x×10−4 m. x=x=x=‾\underline{\hspace{2cm}}​. (Nearest integer) Given: Molar mass of NaCl is 58.5 g mol−158.5 \mathrm{~g} \mathrm{~mol}^{-1}58.5 g mol−1 Molar mass of O2\mathrm{O}_2O2​ is 32 g mol−132 \mathrm{~g} \mathrm{~mol}^{-1}32 g mol−1
Numerical answer
View written solutionFree

Correct answer: 2

  1. Interpret ppm for dissolved oxygen

For dilute solutions in this context, 5.8 ppm5.8\,\text{ppm}5.8ppm means: 5.8 mg of O2 per 1 kg of solution5.8\,\text{mg of } O_2 \text{ per } 1\,\text{kg of solution}5.8mg of O2​ per 1kg of solution

So, in 1000 g1000\,\text{g}1000g of sea water, mass of dissolved O2O_2O2​ is 5.8×10−3 g5.8\times 10^{-3}\,\text{g}5.8×10−3g

  1. Find moles of dissolved oxygen

Molar mass of O2=32 g mol−1O_2 = 32\,\text{g mol}^{-1}O2​=32g mol−1

Hence, n(O2)=5.8×10−332=1.8125×10−4 moln(O_2)=\frac{5.8\times 10^{-3}}{32}=1.8125\times 10^{-4}\,\text{mol}n(O2​)=325.8×10−3​=1.8125×10−4mol

  1. Find mass of NaCl in 1 kg of sea water

Sea water is 6 M6\,\text{M}6M NaCl and density is 2 g mL−12\,\text{g mL}^{-1}2g mL−1.

So, mass of 1 L1\,\text{L}1L solution is 1000 mL×2 g mL−1=2000 g1000\,\text{mL}\times 2\,\text{g mL}^{-1}=2000\,\text{g}1000mL×2g mL−1=2000g

Since it is 6 M6\,\text{M}6M, in 1 L1\,\text{L}1L solution moles of NaCl are 666.

Mass of NaCl in 1 L1\,\text{L}1L solution: 6×58.5=351 g6\times 58.5=351\,\text{g}6×58.5=351g

Therefore, in 2000 g2000\,\text{g}2000g solution, NaCl mass =351 g=351\,\text{g}=351g.

So in 1000 g1000\,\text{g}1000g solution, NaCl mass is 3512=175.5 g\frac{351}{2}=175.5\,\text{g}2351​=175.5g

  1. Find mass of solvent (water) in 1 kg solution

Mass of solvent =1000−175.5=824.5 g=0.8245 kg=1000-175.5=824.5\,\text{g}=0.8245\,\text{kg}=1000−175.5=824.5g=0.8245kg

  1. Calculate molality of dissolved oxygen

Molality, m=moles of solutekg of solventm=\frac{\text{moles of solute}}{\text{kg of solvent}}m=kg of solventmoles of solute​

Thus, m=1.8125×10−40.8245=2.20×10−4 mm=\frac{1.8125\times 10^{-4}}{0.8245}=2.20\times 10^{-4}\,mm=0.82451.8125×10−4​=2.20×10−4m

So, x×10−4=2.20×10−4x\times 10^{-4} = 2.20\times 10^{-4}x×10−4=2.20×10−4

Hence, x≈2x\approx 2x≈2

  1. Final answer

Nearest integer value of xxx is: 2\boxed{2}2​

  1. Comparison with stored answer

Stored correct answer = 222.

Our derived answer matches the stored answer.

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